1-氯-1,2,2,2-四氟乙烷合成路线 （共 83 条）
反应条件
hydrogen; silica gel; nickel T=449.9°C; P=1 Torr; Product distribution;
参考文献
Tomioka, Satoshi; Mori, Tohru; Ueda, Wataru; Morikawa, Yutaka; Ikawa, Tsuneo
Chemistry Letters, 1991 , # 10 p. 1825 - 1826
反应条件
1: With hydrogen fluoride; chromium - based fluorination catalyst T=180°C; 2: With Cr and In on graphite catalyst T=180°C; 4 h; Inconel 600 type reactor; 3: With Cr on active alumina catalyst Inconel 600 type reactor; Product distribution / selectivity;
参考文献
SHOWA DENKO K.K.
Patent: WO2005/92823 A2, 2005 ;
Location in patent: Page/Page column 10-16 ;
反应条件
sodium tetrahydroborate; triethylamine in methanol with 50 percent soln. of (C2H5)3N;
参考文献
Kopaevich, Yu. L.; Belen'kii, G. G.; German, L. S.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , p. 619 - 620
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1973 , p. 646 - 648
Full Text Show Details
Gmelin Handbook: F: PerFHalOrg.SVol.1, 5.3.6, page 174 - 175
反应条件
T=587 - 650°C; Nickel-lined reactor Inconel 617Pyrolysis; Product distribution / selectivity;
参考文献
Noelke, Charles Joseph; Rao, Velliyur Nott Mallikarjuna
Patent: US2005/137430 A1, 2005 ;
Location in patent: Page/Page column 4 ;
反应条件
T=593 - 805°C; Nickel-lined reactor Inconel 617Pyrolysis; Product distribution / selectivity;
参考文献
Noelke, Charles Joseph; Rao, Velliyur Nott Mallikarjuna
Patent: US2005/137430 A1, 2005 ;
Location in patent: Page/Page column 4 ;
反应条件
hydrogenchloride T=660°C; P=760 Torr; Ar-diluted mixtures, flow conditions; other temperatures; Mechanism;
参考文献
Kushina, I. D.; Fedurtsa, M. U.; Gida, V. M.; Barabanov, V. G.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 6.2 p. 1312 - 1315
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , # 6 p. 1433 - 1436
反应条件
hydrogen; palladium/alumina T=100°C; Product distribution; Further Variations:CatalystsPressures;
参考文献
Karpinski; D'Itri
Polish Journal of Chemistry, 2000 , vol. 74, # 10 p. 1421 - 1452
反应条件
hydrogen fluoride; Catalyst M-Chromium oxide T=242°C; 8 h; dehydrochlorination/hydrofluorination; effect of DF substitution for HF; MechanismRate constantProduct distribution;
参考文献
Kavanagh, David M. C.; Ryan, T. Anthony; Mile, Brynmor
Journal of Fluorine Chemistry, 1993 , vol. 64, # 1-2 p. 167 - 176
反应条件
hydrogen; palladium on activated charcoal T=240°C; 0.00611111 h; other times, other temperatures; Product distributionMechanism;
参考文献
Gervasutti, C.; Marangoni, L.; Marra, W.
Journal of Fluorine Chemistry, 1982 , vol. 19, p. 1 - 20
反应条件
chromium fluoride; magnesium(II) fluoride; hydrogen fluoride T=380°C; Kinetics;
参考文献
Dmitriev; Trukshin; Smykalov
Russian Journal of Applied Chemistry, 2002 , vol. 75, # 5 p. 771 - 776
