1-氯-1,2,2,2-四氟乙烷合成路线 （共 83 条）
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 97/3)
参考文献
WO2004/18396 A1, ;
Page 17-18 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 90/10, 12-20 mesh, (1.68 to 0.84 mm) ), prepared from chromium (III) nitrate, cobalt (II) nitrate, ammonia, ammonia nitrate (400°C) T=200 - 425°C; 9.33333 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 17-18 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 90/10, 12-20 mesh, (1.68 to 0.84 mm) ), prepared from chromium (III) nitrate, cobalt (II) nitrate, ammonia (400°C) T=200 - 425°C; 9.33333 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 13-14 ;
反应条件
hydrogen fluoride; Catalyst M-Chromium oxide T=200 - 425°C; 9.33333 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 19-20 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 95/5, 12-20 mesh, (1.68 to 0.84 mm) ), prepared from chromium (III) nitrate, cobalt (II) nitrate, ammonia, ammonia nitrate (400°C) T=200 - 425°C; 9.33333 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 16-17 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 97/3)
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 17-18 ;
反应条件
1: 1,1,1,2-tetrafluoro-2-chloroethane With n-butyllithium in diethyl ether; hexane
T=-80°C; 0.5 h; Inert atmosphere;
2: benzaldehyde in diethyl ether; hexane
T=-80 - 0°C; 5 h; Inert atmosphere; stereospecific reactionFurther stages;
参考文献
Notsu, Keiji; Zushi, Yasuyuki; Ota, Shin; Kawasaki-Takasuka, Tomoko; Yamazaki, Takashi
Chemistry - A European Journal, 2011 , vol. 17, # 33 p. 9200 - 9208
反应条件
hydrogen fluoride; fluorinated chromium oxide
T=320°C; P=2353.83 Torr; 60 h;
参考文献
Daikin Industries, Ltd.
Patent: US6392106 B1, 2002 ;
Location in patent: Page column 5-7 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 90/10, 12-20 mesh, (1.68 to 0.84 mm) ), prepared from chromium (III) nitrate, cobalt (II) nitrate, ammonia, ammonia nitrate (400°C)
T=200 - 425°C; 9.33333 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 14 ;
反应条件
hydrogen fluoride; Catalyst M-Chromium oxide
T=200 - 425°C; 9.33333 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY; Nappa, Mario, J.
Patent: WO2004/18396 A1, 2004 ;
Location in patent: Page 12-13 ;
