1-氟-2,3,5-三溴苯合成路线 (共 2 条)
反应条件
hydrogenchloride; tetrafluoroboric acid; sodium nitrite Erhitzen des Reaktionsprodukts auf 295grad;
参考文献
Pavlath; Olah
Acta Chimica Academiae Scientiarum Hungaricae, 1957 , vol. 10, p. 227,229
反应条件
1: 3-fluoro-1,2,5-tribromobenzene With isopropylmagnesium chloride in tetrahydrofuran T=-40°C; Grignard reaction; 2 h; 2: carbon dioxide in tetrahydrofuran T=-40°C; 1 h; Further stages. Title compound not separated from byproducts.;
参考文献
Menzel, Karsten; Mills, Paul M.; Frantz, Doug E.; Nelson, Todd D.; Kress, Michael H.
Tetrahedron Letters, 2008 , vol. 49, # 3 p. 415 - 418