4,4-二甲基-1-(三甲基硅烷基)戊烷-1,3-二酮合成路线 （共 6 条）
反应条件
mercury dichloride; mercury(II) oxide in methanol; water
T=20°C; 2.5 h;
参考文献
Claessen, Rolf U.; Kornilov, Andrei M.; Banger, Kulbinder K.; Ngo, Silvana C.; Higashiya, Seiichiro; Wells, Christopher C.; Dikarev, Evgeny V.; Toscano, Paul J.; Welch, John T.
Journal of Organometallic Chemistry, 2004 , vol. 689, # 1 p. 71 - 81
反应条件
1: methyl trimethylsilyl ketone With lithium diisopropyl amide in diethyl ether; hexane
T=-85°C;
2: pivaloyl chloride in diethyl ether; hexane
T=-110 - -75°C; 1 h;
参考文献
Banger, Kulbinder K.; Ngo, Silvana C.; Higashiya, Seiichiro; Claessen, Rolf U.; Bousman, Kenneth S.; Lim, Poay N.; Toscano, Paul J.; Welch, John T.
Journal of Organometallic Chemistry, 2003 , vol. 678, # 1-2 p. 15 - 32
反应条件
1.1: n-BuLi / hexane; diethyl ether / -30 °C
1.2: CuBr*Me2S / hexane; diethyl ether / 1 h / -60 °C
1.3: 56 percent / hexane; diethyl ether / -60 - -30 °C
2.1: HgCl2; HgO / methanol; H2O / 2.5 h / 20 °C
View Scheme
参考文献
Claessen, Rolf U.; Kornilov, Andrei M.; Banger, Kulbinder K.; Ngo, Silvana C.; Higashiya, Seiichiro; Wells, Christopher C.; Dikarev, Evgeny V.; Toscano, Paul J.; Welch, John T.
Journal of Organometallic Chemistry, 2004 , vol. 689, # 1 p. 71 - 81
反应条件
in diethyl ether; hexane
T=-110 - -75°C; Claisen Condensation; 1 h;
参考文献
Research Foundation of State University of New York
Patent: US6340768 B1, 2002 ;
Location in patent: Example 1 ;
反应条件
in diethyl ether
T=-78°C; 0.5 h;
参考文献
Research Foundation of State University of New York
Patent: US6340768 B1, 2002 ;
Location in patent: Example 3 ;
反应条件
in diethyl ether; hexane
T=-110 - -75°C; Claisen Condensation; 2 h;
参考文献
Research Foundation of State University of New York
Patent: US6340768 B1, 2002 ;
Location in patent: Example 2 ;
