3,6-二氢-2H-吡喃-4-硼酸频哪醇酯合成路线 （共 11 条）
反应条件
potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in 1,4-dioxane T=80°C;
参考文献
WO2008/153858 A1, ;
Page/Page column 307 ;
WO 2008/153858 A1
反应条件
Grubb's 2nd generation catalyst in dichloromethane 16 h;
参考文献
WO2011/50016 A1, ;
Page/Page column 108 ;
WO 2011/050016 A1
反应条件
N,N'-dimethyl-p-methoxyaniline; (Sc,SFc)-TaniaPhos; palladium diacetate in toluene T=25°C; 16 h; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 131, # 28 p. 9612 - 9613
反应条件
1.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 2 h / -78 °C / Inert atmosphere 1.2: 3 h / 0 °C 2.1: (Sc,SFc)-TaniaPhos; N,N'-dimethyl-p-methoxyaniline; palladium diacetate / toluene / 16 h / 80 °C / Inert atmosphere View Scheme
参考文献
Journal of the American Chemical Society, , vol. 131, # 28 p. 9612 - 9613
反应条件
N,N'-dimethyl-p-methoxyaniline; (Sc,SFc)-TaniaPhos; palladium diacetate in toluene T=80°C; 16 h; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 131, # 28 p. 9612 - 9613
反应条件
(Sc,SFc)-TaniaPhos; palladium diacetate; N,N-dimethyl-aniline in toluene T=25°C; 16 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 131, # 28 p. 9612 - 9613
反应条件
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
参考文献
Synthesis, , # 6 p. 778 - 780
反应条件
1.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 2 h / -78 °C / Inert atmosphere 1.2: 3 h / 0 °C 2.1: SL-W002-1; palladium diacetate; N,N-dimethyl-aniline / 1,4-dioxane / 16 h / 25 °C / Inert atmosphere View Scheme
参考文献
Journal of the American Chemical Society, , vol. 131, # 28 p. 9612 - 9613
反应条件
1: copper(l) chloride; lithium chloride; potassium acetate / N,N-dimethyl-formamide / 0 °C 2: Grubb's 2nd generation catalyst / dichloromethane / 16 h View Scheme
参考文献
WO2011/50016 A1, ;
WO 2011/050016 A1
反应条件
sodium periodate; ammonium acetate in water; acetone 48 h;
参考文献
Patil, Aditi S.; Mo, Dong-Liang; Wang, Heng-Yen; Mueller, Daniel S.; Anderson, Laura L.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 31 p. 7799 - 7803
