in acetonitrile T=5.8 - 44.7°C; stoped-flow technique; kinetics and mechanism of the nucleophilic substitution reaction; activation energy; spectral study; effect of imidazole concentraton on rate constant; effect of triethylamine; Rate constantKineticsMechanism;
参考文献
Journal of Organic Chemistry, , vol. 61, # 8 p. 2657 - 2663
1: With 1,2-ethanedione dioxime; copper(l) chloride; sodium hydroxide in water T=100°C; 24 h; Inert atmospheresealed tube; 2: With hydrogenchloride in water pH=6 - 7;
参考文献
Li, Xufeng; Yang, Daoshan; Jiang, Yuyang; Fu, Hua
Green Chemistry, 2010 , vol. 12, # 6 p. 1097 - 1105
1: 1H-imidazole; dibenzopyrrole With lithium tert-butylate in acetonitrile; tert-butyl alcohol T=20°C; 0.05 h; Glovebox; 2: iodobenzene With copper(l) iodide in acetonitrile; tert-butyl alcohol T=20°C; 2 h; Irradiation;
参考文献
Ziegler, Daniel T.; Choi, Junwon; Munoz-Molina, Jose Maria; Bissember, Alex C.; Peters, Jonas C.; Fu, Gregory C.
Journal of the American Chemical Society, 2013 , vol. 135, # 35 p. 13107 - 13112
