in acetonitrile T=5.8 - 44.7°C; stoped-flow technique; kinetics and mechanism of the nucleophilic substitution reaction; activation energy; spectral study; effect of imidazole concentraton on rate constant; effect of triethylamine; Rate constantKineticsMechanism;
参考文献
Hadd, Andrew G.; Robinson, Alex L.; Rowlen, Kathy L.; Birks, John W.
Journal of Organic Chemistry, 1998 , vol. 63, # 9 p. 3023 - 3031
in acetonitrile T=5.8 - 44.7°C; stoped-flow technique; kinetics and mechanism of the nucleophilic substitution reaction; activation energy; spectral study; effect of imidazole concentration of rate constant; effect of triethylamine; Rate constantKineticsMechanism;
参考文献
Hadd, Andrew G.; Birks, John W.
Journal of Organic Chemistry, 1996 , vol. 61, # 8 p. 2657 - 2663