1H-1,2,3-三氮唑合成路线 （共 105 条）
反应条件
caesium carbonate; copper(II) oxide; iron (III) acetylacetonate in N,N-dimethyl-formamide
T=90°C; 30 h;
参考文献
Taillefer, Marc; Xia, Ning; Ouali, Armelle
Angewandte Chemie - International Edition, 2007 , vol. 46, # 6 p. 934 - 936
反应条件
3,4,5,6-tetramethyl-t-Bu-X-Phos; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) in toluene
T=120°C; 5 h; Inert atmosphere; regioselective reaction;
参考文献
Ueda, Satoshi; Ali, Siraj; Fors, Brett P.; Buchwald, Stephen L.
Journal of Organic Chemistry, 2012 , vol. 77, # 5 p. 2543 - 2547
反应条件
caesium carbonate; Fe(acac)3; copper(II) oxide in N,N-dimethyl-formamide
T=90°C; 30 h; sealed tube; Conversion of starting material;
参考文献
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.); Ecole Nationale Superieure de Chimie de Montpellier
Patent: WO2008/4088 A2, 2008 ;
Location in patent: Page/Page column 49-50 ;
反应条件
iron; copper; caesium carbonate
T=90 - 120°C;
参考文献
Shi, Suping; Liu, Wei; He, Ping; Kuang, Chunxiang
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 22 p. 3576 - 3580
反应条件
1: With sodium hydride in N,N-dimethyl-formamide
T=20°C;
2: With platinum(IV) oxide; hydrogen in tetrahydrofuran
T=20°C;
参考文献
MERCK CANADA INC.; BOYD, Michael John; CHIASSON, Jean-François; CRANE, Sheldon; GIROUX, André
Patent: WO2013/59928 A1, 2013 ;
Location in patent: Page/Page column 33-34 ;
