1-(1-甲基环己基)乙酮合成路线 （共 27 条）
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
T=80°C; Title compound not separated from byproducts;
参考文献
Curran, Dennis P.; Gu, Xin; Zhang, Wei; Dowd, Paul
Tetrahedron, 1997 , vol. 53, # 27 p. 9023 - 9042
反应条件
chlorosulphonyl isocyanate in benzene
1.) 0 deg C, 2.) reflux, 0.5 h;
参考文献
Joseph, Sajan P.; Dhar, D. N.
Synthetic Communications, 1988 , vol. 18, # 18 p. 2295 - 2302
反应条件
1: aq. KMnO4, KOH, MgSO4 / methanol / 1.) r.t., 2. ) reflux
2: 30 percent Chromat. / Zn<Hg>, aq. HCl / 1.5 h / Heating
View Scheme
参考文献
Bailey, Karen E.; Davis, Brian R.
Australian Journal of Chemistry, 1995 , vol. 48, # 11 p. 1827 - 1834
反应条件
barium dihydroxide in methanol; water
16 h; Heating;
参考文献
Qureshi, M. I.
Acta Chimica Academiae Scientiarum Hungaricae, 1981 , vol. 108, # 3 p. 215 - 218
反应条件
diethyl ether
T=-10°C; Erhitzen des vom Aether befreiten Reaktionsgemisches auf 130grad;
参考文献
Sackur
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1939 , vol. 208, p. 1092
反应条件
1: SOCl2, Py / diethyl ether
2: CuCl / diethyl ether
View Scheme
参考文献
Rouzaud,J. et al.
Bulletin de la Societe Chimique de France, 1965 , p. 2030 - 2037
反应条件
1.1: hydrogenchloride; water / methanol / 2 h / Inert atmosphere; Reflux
2.1: diethyl ether / 4.5 h / 0 - 20 °C / Inert atmosphere
2.2: Inert atmosphere; Cooling with ice
View Scheme
参考文献
Tsubo, Tatsuyuki; Chen, Hsiu-Hui; Yokomori, Minako; Fukui, Kosuke; Kikuchi, Satoshi; Yamada, Tohru
Chemistry Letters, 2012 , vol. 41, # 8 p. 780 - 782
反应条件
hydrogenchloride; p-NO2-benzenesulfonyl azide
1.) benzene, 90 deg C, protection from light, 10.5 d 2.) aq. ethanol, 50 deg C, 1 d; Yield given. Multistep reaction;
参考文献
McManus, Samuel P.; Ortiz, Margarita; Abramovitch, Rudolph A.
Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 336 - 342
反应条件
copper(l) chloride in diethyl ether
参考文献
Rouzaud,J. et al.
Bulletin de la Societe Chimique de France, 1965 , p. 2030 - 2037
反应条件
hydrogenchloride; p-NO2-benzenesulfonyl azide
1.) benzene, 90 deg C, protection from light, 10.5 d 2.) aq. ethanol, 50 deg C, 3 d; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
McManus, Samuel P.; Ortiz, Margarita; Abramovitch, Rudolph A.
Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 336 - 342
