双环[2.2.1]庚-2-烯-6-醇合成路线 （共 8 条）
反应条件
1: 48 percent / CrO3; pyridine / CH2Cl2 / 48 h 2: 77 percent / L-Selectride / tetrahydrofuran / 4 h / -78 - -20 °C 3: 37 percent / pyridine; dimethylaminopyridine / CH2Cl2 / 24 h View Scheme
参考文献
Mayo, Peter; Tam, William
Tetrahedron, 2002 , vol. 58, # 47 p. 9513 - 9525
反应条件
nickel T=135 - 140°C; 24 h; Heating;
参考文献
Prasad, J. V. N. Vara; Pillai, C. N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, p. 998 - 999
反应条件
ammonia; lithium; tert-butyl alcohol in tetrahydrofuran T=-33°C; 0.166667 h;
参考文献
Cotsaris, Evangelo; Paddon-Row, Michael N.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 9 p. 1487 - 1500
反应条件
pyridine; 4-(N,N-dimethlyamino)pyridine in dichloromethane Ambient temperature;
参考文献
Oberhauser, Th.; Bodenteich, M.; Faber, K.; Penn, G.; Griengl, H.
Tetrahedron, 1987 , vol. 43, # 17 p. 3931 - 3944
反应条件
Sarett’s reagent in dichloromethane 2 h; Ambient temperature;
参考文献
Fischer, Walter; Grob, Cyril A.; Sprecher, Georg von; Waldner, Adrian
Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 816 - 823
反应条件
ammonia; lithium; tert-butyl alcohol in tetrahydrofuran T=-33°C; 0.166667 h;
参考文献
Cotsaris, Evangelo; Paddon-Row, Michael N.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984 , # 9 p. 1487 - 1500
反应条件
in pentane
Irradiation; Yield given. Yields of byproduct given;
参考文献
Studebaker, Joel; Srinivasan, R.; Ors, Jose A.; Baum, Thomas
Journal of the American Chemical Society, 1980 , vol. 102, # 22 p. 6872 - 6874
反应条件
in pentane
Irradiation; Yield given. Yields of byproduct given;
参考文献
Studebaker, Joel; Srinivasan, R.; Ors, Jose A.; Baum, Thomas
Journal of the American Chemical Society, 1980 , vol. 102, # 22 p. 6872 - 6874
