1,3,5,7,2,4,6,8-四硫杂四氮杂环辛四烯合成路线 （共 142 条）
反应条件
very contaminated (sulfur);;
参考文献
Soubeiran, E.
Ann. Chim. Phys., 1838 , vol. 67, p. 71 - 103
Full Text Show Details
Soubeiran, E.
Journal fuer Praktische Chemie (Leipzig), 1838 , vol. 13, p. 449 - 474
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 4, page 1537 - 1540
反应条件
chlorine in not given
oxidation;;
参考文献
Gmelin Handbook: S: MVol.B3, 4, page 1537 - 1540
反应条件
in dichloromethane
byproducts: (CH3)3SiCl, N2; a soln. of Si compd. added to a suspn. of TeCl4 at -80°C, stirredovernight, allowed to warm to room temp.; sepd., addnl. crystd. at room temp.;
参考文献
Konu, Jari; Ahlgren, Markku; Aucott, Stephen M.; Chivers, Tristram; Dale, Sophie H.; Elsegood, Mark R. J.; Holmes, Kathryn E.; James, Sarah L. M.; Kelly, Paul F.; Laitinen, Risto S.
Inorganic Chemistry, 2005 , vol. 44, # 14 p. 4992 - 5000
反应条件
in pentane
(under exclusion of moisture); addn. of NSF to a soln. of the sulfurdiimide in pentane in a pressure-tight apparatus at -195°C, slow warming to room temp. with stirring; decanting, evapn. of the volatiles;
参考文献
Isenberg, W.; Mews, R.; Sheldrick, G. M.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1985 , vol. 525, p. 54 - 66
反应条件
in N2 atmosphere;by silent electric discharge;;
参考文献
Deshmukh, G. S.; Sirsikar, S.
Pr. Indian Acad. Sci., 1948 , vol. A 28, p. 175 - 184
反应条件
in tetrachloromethane
introduction of dry NH3 into S2Cl2 dild. in dry CCl4; stirring (30-50°C); after 5-6 h discoloration to salmon red;; removal of NH4Cl (extraction/water); evapn. (from CCl4); drying on clay;extraction of S7NH (acetone);;
参考文献
Goehring, M.; Herb, H.; Koch, W.
Z. Anorg. Chem., 1951 , vol. 264, p. 137 - 143
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 12, page 1554 - 1556
Full Text Show Details
Imperial Chemical Industries Ltd.
Patent: US2382845 , 1945 ;
反应条件
nitrogen(IV) oxide in diethyl ether
oxidation;;
参考文献
Fluck, E.; Becke-Goehring, M.
Z. Anorg. Chem., 1957 , vol. 292, p. 229 - 231
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 15, page 1560 - 1562
反应条件
in dichloromethane
Electrolysis; electrolysis of (S5N5)FeCl4 in CH2Cl2 at -19°C (0.1 M (Bu4N)BF4,0.5 mA/cm**2); filtn., cooling to -20°C, pptn. of S4N4, evapn. of solvent in vacuo, extn. with pentane yields further S4N4, removal of product from theelectrode under N2 or Ar, washing with CH2Cl2, drying in vacuo;
参考文献
Fritz, Heinz P.; Bruchhaus, Rainer
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1983 , vol. 38, # 11 p. 1375 - 1382
反应条件
pyridine in pyridine
evolution of heat;;
参考文献
Gmelin Handbook: S: MVol.B3, 152, page 1851 - 1854
Full Text Show Details
Rochus, V.
Diss. Berlin 1906, S. 25
反应条件
in sulfur dioxide
byproducts: N2; SO2 was condenced onto frozen mixt. of (S3N2)2NAsF6 and CsN3 (molar ratio 200:1:1), warmed to 0°C with stirring, 30 min; filtered, washed with SO2, pumped, CH3CN condenced into vessel, washed with CH3CN; identified by IR spectra;
参考文献
MacLean, Gregory K.; Passmore, Jack; White, Peter S.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 211 - 218
