1,3,5,7,2,4,6,8-四硫杂四氮杂环辛四烯合成路线 （共 142 条）
反应条件
mixture of S2Cl2 and inert material (e. g. NH4Cl or NaCl or talc or bentonite) treated with ammonia containing gas; cooling (vigorous reaction); end of reaction is discoloration from violet to yellow;; leaching (water); mixture of S4N4 and sulfur obtained;;
参考文献
Gmelin Handbook: S: MVol.B3, 5, page 1540 - 1543
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Harshaw Chemical Co.
Patent: US2190177 , 1940 ;
反应条件
in water; acetone
byproducts: nitrite; aq. acetone; formation of NO3(1-) containing compound;;
参考文献
Goehring, M.; Weiss, J.; Zirker, G.
Z. Anorg. Chem., 1955 , vol. 278, p. 1 - 11
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 15, page 1560 - 1562
反应条件
in pyridine
byproducts: acetic acid; small amount of Hg(II) acetate;;
参考文献
Meuwsen, A.; Loesel, M.
Z. Anorg. Chem., 1953 , vol. 271, p. 217 - 220
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 15, page 1560 - 1562
反应条件
in diethyl ether
volume reduced, heated, MS, IR;
参考文献
Herberhold, Max; Jellen, Wolfgang; Buehlmeyer, Wolfgang; Ehrenreich, Wolfgang; Reiner, Josef
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985 , vol. 40, # 10 p. 1229 - 1232
反应条件
nitrogen
active nitrogen;;
参考文献
Moldenhauer, W.; Zimmermann, A.
Ber., 1929 , vol. 62, p. 2390 - 2392
反应条件
in further solvent(s)
dipping into vapour of boiling aniline (vacuum); further byproduct: brown featherlike needles;;
参考文献
Burt, F. P.
Journal of the Chemical Society, 1910 , vol. 97, p. 1171 - 1174
反应条件
in ammonia
S(2-) was pptd. with AgI; the residue was evaporated;
参考文献
Ruff, O.; Geisel, E.
Ber., 1905 , vol. 38, p. 2659 - 2667
反应条件
in ammonia
condensing liquid NH3 on solid sulphur, dissoln. within 1 d (handling of solns. in the dark under high vac., -35°C); investigation of equilibrium by EMF-measurements and light absorption spectra; discussion of photosensitive intermediates;; not isolated;;
参考文献
Prestel, H.; Seelert, S.; Schindewolf, U.
Zeitschrift fuer Physikalische Chemie (Muenchen, Germany), 1986 , vol. 148, p. 97 - 104
反应条件
in diethyl ether
S2Cl2 dild. in ether; introduction of dry NH3 (cooling);; filtration from NH4Cl; evapn. to dryness; recrystn. CHCl3/alc. for pptn.); cooling causes low yield of S4N4 bur high yield of S7NH;;
参考文献
Gmelin Handbook: S: MVol.B3, 4, page 1537 - 1540
反应条件
in carbon disulfide
byproducts: NH4Cl; introduction of NH3 gas into soln. of S2Cl2 (common temps.) until discoloration to orange yellow; formation of further sulfur containing compounds;; filtration; S4N4 first crystallizing fraction; multiple extraction (boiling CS2);;
参考文献
Gmelin Handbook: S: MVol.B3, 4, page 1537 - 1540
