反应条件
1: 86 percent / pyridinium chlorochromate, sodium acetate / CH2Cl2 / 0.75 h / 25 °C
2: 1.) sodium hydride / 1.) ether, 25 deg C, 45 min, 2.) 3 h
3: 98 percent / hydrogen / 5percent Pd-C / methanol / 12 h / 25 °C
4: 93 percent / lithium aluminum hydride / diethyl ether / 2 h / 0 °C
5: 95 percent / pyridine
6: 1.) sodium iodide, 2.) DBU / 1.) DMF, 50 deg C, 3.5 h, 2.) 80 deg C, 3.5 h
7: 95 percent / m-chloroperbenzoic acid
View Scheme
参考文献
Dhokte, U. P.; Rao, A. S.
Synthetic Communications, 1988 , vol. 18, # 8 p. 811 - 822
