5,10,15,20-四(4-溴苯基)卟啉合成路线 （共 11 条）
反应条件
1: With boron trifluoride diethyl etherate in chloroform
1 h;
2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in chloroform
1 h; Further stages.;
参考文献
Capitosti, Gregory J.; Guerrero, Carol D.; Binkley Jr., David E.; Rajesh, Cheruvallil S.; Modarelli, David A.
Journal of Organic Chemistry, 2003 , vol. 68, # 2 p. 247 - 261
反应条件
1: CF3SO2Cl / CH2Cl2 / 1 h / 20 °C
2: air / CH2Cl2 / 3 h / 39 °C
View Scheme
参考文献
Sharghi, Hashem; Nejad, Alireza Hassani
Tetrahedron, 2004 , vol. 60, # 8 p. 1863 - 1868
反应条件
1: With methanesulfonic acid in dichloromethane
0.5 h;
2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane
0.166667 h;
参考文献
Shaw, Janet L.; Garrison, Shana A.; Aleman, Elvin A.; Ziegler, Christopher J.; Modarelli, David A.
Journal of Organic Chemistry, 2004 , vol. 69, # 22 p. 7423 - 7427
反应条件
1: With boron trifluoride diethyl etherate in dichloromethane
3 h;
2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in dichloromethane
参考文献
Stute, Silvio; Gloe, Kerstin; Gloe, Karsten
Tetrahedron, 2005 , vol. 61, # 11 p. 2907 - 2912
反应条件
4-bromo-benzaldehyde in propionic acid
2 h; Heatingcooling overnight; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Milgrom, Lionel R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1483 - 1487
反应条件
4-methoxy-benzaldehyde in propionic acid
2 h; Heatingcooling overnight; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Milgrom, Lionel R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1483 - 1487
反应条件
hydrogen bromide; sodium nitrite
1)5 deg C, 2)100 deg. C; Yield given. Multistep reaction;
参考文献
Semeikin, A.S.; Koifman, O.I.; Berezin, B.D.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1986 , vol. 22, # 4 p. 397 - 401
Khimiya Geterotsiklicheskikh Soedinenii, 1986 , vol. 22, # 4 p. 486 - 490
反应条件
chloranil; trifluoroacetic acid
1.) CH2Cl2, 1 h 2.) CH2Cl2, 1 h, reflux; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Narayanan, Seenichamy Jeyaprakash; Sridevi, Bashyam; Srinivasan, Alagar; Chandrashekar, Tavarekere K.; Roy, Raja
Tetrahedron Letters, 1998 , vol. 39, # 40 p. 7389 - 7392
反应条件
benzaldehyde; propionic acid
0.5 h; Heating; Further byproducts given. Title compound not separated from byproducts;
参考文献
Martensson, Jerker; Sandros, Kjell; Wennerstroem, Olof
Journal of Physical Organic Chemistry, 1994 , vol. 7, # 10 p. 534 - 544
反应条件
in propionic acid
2 h; Heatingcooling overnight; Further byproducts given. Yields of byproduct given;
参考文献
Milgrom, Lionel R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 7 p. 1483 - 1487
