反应条件
in chloroform
cold (10°C) satd. soln. of dry NH3 in CHCl3 added to icecold soln. of S2Cl2 in CHCl3 (vigorous stirring); when becoming alkaline, filtration (from NH4Cl/S), washing (CHCl3) and further addn. of S2Cl2 and NH3; (all repeated until S4N4 appears);; removal of S4N4 and S (denaturated spirit of wine); fractionated crystn.; recrystn. (CS2);;
参考文献
Macbeth, A. K.; Graham, H.
Proceedings of the Royal Irish Academy, Section B: Biological, Geological and Chemical Science, 1921 , vol. 36, p. 31 - 40
Full Text Show Details
Gmelin Handbook: S: MVol.B3, 12, page 1554 - 1556