in tetrachloromethane
Irradiation (UV/VIS); high pressure Hg-lamp (125 W, 250-350 nm) or exposing to sunlight for 1- 2 months; detd. by UV spectroscopy;
in neat (no solvent)
byproducts: S; explosion of COS with O2, dependence of inflammation temps. and pressure limits from surface activity;; pptn. of CS (and S) on walls;;
参考文献
Bawn, C. E. H.
Journal of the Chemical Society, 1933 , p. 145 - 151
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Gmelin Handbook: S: MVol.B1, 90, page 198 - 200
in gas
Kinetics; byproducts: CO; reacting atomic carbon (from microwave dissociation of CO dild. in He) in a fast flow react., room temp.; monitoring by CS chemiluminescence;
参考文献
Dorthe, G.; Caubet, Ph.; Vias, Th.; Barrere, B.; Marchais, J.
Journal of Physical Chemistry, 1991 , vol. 95, # 13 p. 5109 - 5116