1-BOC-吡咯-2-羧酸甲酯合成路线 （共 9 条）
反应条件
1: methanol 2: cyclohexane View Scheme
参考文献
Synthesis, , # 14 p. 2367 - 2375
参考文献
Synthesis, , # 14 p. 2367 - 2375
反应条件
hydrogen; triethylamine; (S,S)-(R,R)-PhTRAP in isopropyl alcohol T=80°C; P=38002.6 Torr; 24 h; Title compound not separated from byproducts.;
参考文献
Kuwano, Ryoichi; Kashiwabara, Manabu; Ohsumi, Masato; Kusano, Hiroki
Journal of the American Chemical Society, 2008 , vol. 130, # 3 p. 808 - 809
反应条件
bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); 4,4'-di-tert-butyl-2,2'-dipyridyl in hexane T=20°C; 5 h; Inert atmosphere; regioselective reaction;
参考文献
Kallepalli, Venkata A.; Shi, Feng; Paul, Sulagna; Onyeozili, Edith N.; Maleczka Jr., Robert E.; Smith III, Milton R.
Journal of Organic Chemistry, 2009 , vol. 74, # 23 p. 9199 - 9201
反应条件
di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; 4,4'-di-tert-butyl-2,2'-dipyridyl in hexane T=100°C; 1 h; Microwave irradiation;
参考文献
McMurray, Lindsay; Beck, Elizabeth M.; Gaunt, Matthew J.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 37 p. 9288 - 9291
Angew. Chem. Int. Ed., 2012 , vol. 124, # 37 p. 9422 - 9425,4
反应条件
1: liquid ammonia / -78 °C 2: 45 percent / aq. NaHCO3; Novozym(R) View Scheme
参考文献
Bernard, Harald; Buelow, Gerd; Lange, Udo E. W.; Mack, Helmut; Pfeiffer, Thomas; Schaefer, Bernd; Seitz, Werner; Zierke, Thomas
Synthesis, 2004 , # 14 p. 2367 - 2375
反应条件
1: With di-(2-methoxyethyl)amine; 4,4'-di(tert-butyl)-[1,1-biphenyl]yllithium in tetrahydrofuran T=-78°C; 0.0833333 h; 2: With (S)-4-benzyl-5,5-diphenyl-2-oxazolidine in tetrahydrofuran 1 h; Further stages.;
参考文献
Carbery, David R.; Donohoe, Timothy J.
Chemical Communications, 2004 , # 6 p. 722 - 723
反应条件
hydrogen; triethylamine; (S,S)-(R,R)-PhTRAP in isopropyl alcohol T=80°C; P=38002.6 Torr; 24 h; Title compound not separated from byproducts.;
参考文献
Kuwano, Ryoichi; Kashiwabara, Manabu; Ohsumi, Masato; Kusano, Hiroki
Journal of the American Chemical Society, 2008 , vol. 130, # 3 p. 808 - 809
反应条件
potassium phosphate in methanol T=120°C; P=5171.62 Torr; 0.0333333 h; Microwave irradiation;
参考文献
Dandepally, Srinivasa Reddy; Williams, Alfred L.
Tetrahedron Letters, 2009 , vol. 50, # 9 p. 1071 - 1074
