2-(2’-吡啶)-苯胺合成路线 （共 22 条）
反应条件
1: 75 percent / PdCl2(PPh3)2 / tetrahydrofuran / 24 h / 110 °C 2: CuSO4, NaBH4 / ethanol; H2O / 3 h / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 48, # 22 p. 4601 - 4616
反应条件
1: 75 percent / PdCl2(PPh3)2 / tetrahydrofuran / 24 h / 110 °C 2: CuSO4, NaBH4 / ethanol; H2O / 3 h / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 48, # 22 p. 4601 - 4616
反应条件
1: 2-bromo-pyridine With isopropylmagnesium chloride in tetrahydrofuran T=30°C; 3.5 h; 2: With zinc(II) chloride in tetrahydrofuran T=20°C; 1.66667 h; 3: 2-iodo aniline With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran 24 h; Reflux;
参考文献
Organic and Biomolecular Chemistry, , vol. 12, # 2 p. 286 - 297
反应条件
copper(I) oxide; ammonium hydroxide in ethanol; water T=25 - 45°C; 4 h;
参考文献
Niu, Liting; Yang, Haijun; Yang, Daoshan; Fu, Hua
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 11-12 p. 2211 - 2217
反应条件
2,2'-azo-bisisobutyronitrile; diphenyl diselenide; tri-n-butyl-tin hydride T=95°C; 17 h;
参考文献
Heterocycles, , vol. 64, p. 499 - 504
反应条件
1: 1.) diazotization 2: SnCl2 / HCl View Scheme
参考文献
Australian Journal of Chemistry, , vol. 50, # 2 p. 109 - 114
反应条件
1: 1.) diazotization 2: SnCl2 / HCl View Scheme
参考文献
Australian Journal of Chemistry, , vol. 50, # 2 p. 109 - 114
反应条件
1: [{(η5-C5Me5)RhCl}2(μ-Cl)2]; [bis(acetoxy)iodo]benzene; toluene-4-sulfonic acid; sodium azide / acetone / 3 h / 50 °C 2: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 45 p. 11862 - 11866
Angew. Chem., , vol. 125, # 45 p. 12078 - 12082,5
参考文献
Journal of the American Chemical Society, , vol. 73, p. 2626,2629
反应条件
1: 1) conc. HCl, NaNO2, 2) NaN3, NaOAc / 1) H2O, 0 deg C, 1 h, 2) water, 0 deg C, 1 h 2: 90 percent / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
Molina; Lorenzo; Aller
Tetrahedron, 1992 , vol. 48, # 22 p. 4601 - 4616
