2-叔丁基-3,3-二甲基丁酰氯合成路线 （共 25 条）
反应条件
thionyl chloride in tetrachloromethane T=55°C; 43 h; Inert atmosphere;
参考文献
Knorr, Rudolf; Hennig, Karsten-Olaf; Schubert, Bernhard; Boehrer, Petra
European Journal of Organic Chemistry, 2010 , # 34 p. 6651 - 6664
反应条件
2: SOCl2 / pyridine 3: (i) NaBH4, AlCl3, diglyme, (ii) NaOH, aq. H2O2, EtOH 4: H2SO4, AcOH, CrO3, H2O 5: SOCl2 View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
1: SOCl2 / pyridine 2: (i) NaBH4, AlCl3, diglyme, (ii) NaOH, aq. H2O2, EtOH 3: H2SO4, AcOH, CrO3, H2O 4: SOCl2 View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
1: 1) BH3*THF; 2) 30percent aq. H2O2, NaOH / 1) r.t., 4 h; 2) EtOH, r.t., 1 h 2: 85 percent / CrO3, aq. H2SO4 / acetone / 4 h / Ambient temperature; ultrasound sonication 3: 86 percent / SOCl2 / 1 h / 60 - 65 °C View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
1: 85 percent / CrO3, aq. H2SO4 / acetone / 4 h / Ambient temperature; ultrasound sonication 2: 86 percent / SOCl2 / 1 h / 60 - 65 °C View Scheme
参考文献
Newman,M.S. et al.
Journal of the American Chemical Society, 1960 , vol. 82, p. 2498 - 2501
反应条件
2: aq. HCl 3: (i) aq. H3PO4, (ii) SOCl2 View Scheme
参考文献
Back,T.G. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 2079 - 2089
反应条件
1: aq. HCl 2: (i) aq. H3PO4, (ii) SOCl2 View Scheme
参考文献
Back,T.G. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 2079 - 2089
反应条件
(i) aq. H3PO4, (ii) SOCl2; Multistep reaction;
参考文献
Back,T.G. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 2079 - 2089
反应条件
hydrogenchloride in diethylene glycol dimethyl ether; water T=55°C; Pummerer reaction; 6.5 h; Mechanism;
参考文献
Knorr, Rudolf
European Journal of Organic Chemistry, 2011 , # 31 p. 6335 - 6342
反应条件
tetrachloromethane; 4-(N,N-dimethlyamino)pyridine; Fonderma 3 h; Heating;
参考文献
Stofer, Edmond; Lion, Claude
Bulletin des Societes Chimiques Belges, 1987 , vol. 96, # 8 p. 623 - 628
