(3beta,7alpha,15alpha)-3,7,15-三羟基雄甾-5-烯-17-酮合成路线 (共 3 条)
反应条件
randomly methylated β-cyclodextrin in water; N,N-dimethyl-formamide T=29°C; pH=6.0; 30 h;
参考文献
Steroids, , vol. 74, # 2 p. 233 - 237
反应条件
Colletotrichum lini 36 h;
参考文献
Angewandte Chemie, , vol. 95, # 5 p. 413 - 414
反应条件
1: 97 percent / 35 percent HClO4 / various solvent(s) / 4 h / Ambient temperature
2: 90 percent / 4-dimethylaminopyridine / pyridine / 4 h / 50 °C
3: 91 percent / NaOH / dimethylsulfoxide / 1 h / Ambient temperature
View Scheme
参考文献
Petzoldt, Karl; Laurent, Henry; Wiechert, Rudolf
Angewandte Chemie, 1983 , vol. 95, # 5 p. 413 - 414