3-(3-苯基-2-丙基)-2,4-戊二酮合成路线 （共 17 条）
反应条件
1: acetylacetone With sodium hydride 2: ethyl 1-phenylallyl carbonate With (pentamethylcyclopentadienyl)Ru(1,5-cyclooctadiene)Cl; bis(mesityl)ethylenediimine in tetrahydrofuran T=20°C; 16 h; Title compound not separated from byproducts;
参考文献
Synlett, , # 3 p. 408 - 410
反应条件
1,3-bis(2-methoxyethyl)benzimidazolium chloride; [Cp*Ru(CNCH3)3]+PF6- in acetonitrile T=20°C; 16 h;
参考文献
Tetrahedron Letters, , vol. 47, # 4 p. 535 - 538
反应条件
1: acetylacetone With potassium carbonate in acetone T=20°C; 0.25 h; Inert atmosphere; 2: 1-[(E)-3-bromo-1-propenyl]benzene in acetone T=80°C; RefluxInert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 41 p. 4667 - 4669
反应条件
copper; Cu(II) perchlorate in tetrahydrofuran 6 h; Heating; Yield given;
参考文献
Journal of Organometallic Chemistry, , vol. 361, p. C57 - C60
反应条件
1.1: N,N-dimethyl-formamide / |Inert atmosphere 2.1: diisobutylaluminium hydride / dichloromethane / 0.5 h / -78 °C / |Inert atmosphere 2.2: 1 h / -78 - 0 °C / |Inert atmosphere 3.1: [Cp*Ir(SnCl3)2{SnCl2(H2O)2}] / dichloromethane / 20 °C / |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Tetrahedron, , vol. 69, # 2 p. 942 - 956
反应条件
1.1: diisobutylaluminium hydride / dichloromethane / 0.5 h / -78 °C / |Inert atmosphere 1.2: 1 h / -78 - 0 °C / |Inert atmosphere 2.1: [Cp*Ir(SnCl3)2{SnCl2(H2O)2}] / dichloromethane / 20 °C / |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Tetrahedron, , vol. 69, # 2 p. 942 - 956
反应条件
in tetrahydrofuran T=45°C; in terms of catalysts and reagents; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 331, # 1 p. 121 - 138
