5H-二苯并[a,d]环庚烯合成路线 （共 24 条）
反应条件
1: CCl4; N-bromo-succinimide
2: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: NaBH4; methanol; aqueous NaOH
2: H3BO3 / 205 °C / 0.5 Torr
3: CCl4; N-bromo-succinimide
4: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: benzoyl peroxide; CCl4; N-bromo-succinimide
2: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: H3BO3 / 205 °C / 0.5 Torr
2: CCl4; N-bromo-succinimide
3: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: polyphosphoric acid
2: NaBH4; methanol; aqueous NaOH
3: H3BO3 / 205 °C / 0.5 Torr
4: CCl4; N-bromo-succinimide
5: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: 2-methyl-pyridine
2: CCl4; N-bromo-succinimide
3: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: toluene-4-sulfonic acid; benzene
2: polyphosphoric acid
3: NaBH4; methanol; aqueous NaOH
4: H3BO3 / 205 °C / 0.5 Torr
5: CCl4; N-bromo-succinimide
6: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: CCl4; N-bromo-succinimide
2: quinoline / 125 - 130 °C
View Scheme
参考文献
Cope; Fenton
Journal of the American Chemical Society, 1951 , vol. 73, p. 1668,1672
反应条件
1: sodium; THF; tetraphenylethene / -80 °C
2: CCl4; N-bromo-succinimide
3: quinoline / 125 - 130 °C
View Scheme
参考文献
Cope; Fenton
Journal of the American Chemical Society, 1951 , vol. 73, p. 1668,1672
反应条件
quinoline; copper (II) chromite
T=210 - 220°C;
参考文献
Bergmann,E.D.; Solomonovici,A.
Synthesis, 1970 , p. 183 - 189
