甲基-2-脱氧-L-赤式戊呋喃糖合成路线 （共 38 条）
反应条件
1: CF3CO2H-H2O / 3 h / Ambient temperature 2: disiamylborane<(Sia2BH)2> / tetrahydrofuran / 22 h / Ambient temperature View Scheme
参考文献
Tetrahedron Letters, , vol. 26, # 47 p. 5777 - 5780
反应条件
T=20°C; P=0 Torr; low energy electron beam; Quantum yieldProduct distribution;
参考文献
Zheng, Yi; Cloutier, Pierre; Hunting, Darel J.; Wagner, J. Richard; Sanche, Leon
Journal of the American Chemical Society, 2004 , vol. 126, # 4 p. 1002 - 1003
反应条件
1: 2 h / 90 °C 2: sodium tetrahydroborate / aq. acetic acid View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 57, # 10 p. 2399 - 2400,2145 - 2146
反应条件
1: 90.4 percent / DIBAL / toluene / 0.25 h / -78 °C 2: 62 percent / AcOH / tetrahydrofuran; H2O / 24 h / 60 - 70 °C View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 49, # 5 p. 1435 - 1440
反应条件
1: 67 percent / AcOH / tetrahydrofuran; H2O / 72 h / Ambient temperature 2: CF3COOH / H2O / 2 h / Ambient temperature 3: imidazole / dimethylformamide / 3 h / Ambient temperature 4: 90.4 percent / DIBAL / toluene / 0.25 h / -78 °C 5: 62 percent / AcOH / tetrahydrofuran; H2O / 24 h / 60 - 70 °C View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 49, # 5 p. 1435 - 1440
反应条件
dimethylsulfide; ozone 1. O3 2. Me2S; Multistep reaction;
参考文献
Chemistry Letters, , p. 1109 - 1110
反应条件
1: 70 percent / bis(3-methyl-2-butyl)borane / 24 h / Ambient temperature 2: 73 percent / MeONa View Scheme
参考文献
Chemistry Letters, , p. 241 - 244
反应条件
1: 87 percent / trifluoroacetic acid, water 2: 79 percent / bis(3-methyl-2-butyl)borane / 24 h / Ambient temperature View Scheme
参考文献
Chemistry Letters, , p. 241 - 244
反应条件
1: 68 percent / trifluoroacetic acid, water 2: 70 percent / bis(3-methyl-2-butyl)borane / 24 h / Ambient temperature 3: 73 percent / MeONa View Scheme
参考文献
Chemistry Letters, , p. 241 - 244
反应条件
potassium chloride T=37°C; hydrolysis at various pH: 4 - 7.5; Rate constant;
参考文献
Journal of Organic Chemistry, , vol. 56, # 16 p. 5009 - 5010
