顺式-4-环戊烯-1,3-二醇合成路线 （共 46 条）
反应条件
1: 36 percent / DBU / CH2Cl2 / 72 h / Ambient temperature 2: LiAlH4, LiI / toluene; various solvent(s) / 1.) -20 deg C, 1 h, 2.) -20 deg C to 0 deg C, 0.5 h, 3.) 0 deg C to 15 deg C, 4 h 3: 58 mg / p-TsOH / ethanol / 8 h / 55 °C View Scheme
参考文献
Tetrahedron, , vol. 53, # 6 p. 1983 - 2004
反应条件
methanol; potassium carbonate in diethyl ether 4 h;
参考文献
Tetrahedron Asymmetry, , vol. 10, # 11 p. 2139 - 2152
反应条件
potassium carbonate in methanol T=0°C; 4 h;
参考文献
Tietze, Lutz F.; Stadler, Christian; Boehnke, Niels; Brasche, Gordon; Grube, Alexander
Synlett, 2007 , # 3 p. 485 - 487
反应条件
oxygen; rose bengal; thiourea in methanol T=20°C; 12 h; Irradiation;
参考文献
Gurjar, Mukund K.; Reddy, Challa Nageswar; Kalkote, Uttam R.; Chorghade, Mukund S.
Heterocycles, 2009 , vol. 77, # 2 p. 909 - 925
反应条件
sodium tetrahydroborate; cerium(III) chloride in methanol
参考文献
Zuercher, William J.; Hashimoto, Masakazu; Grubbs, Robert H.
Journal of the American Chemical Society, 1996 , vol. 118, # 28 p. 6634 - 6640
反应条件
tris(triphenylphosphine)ruthenium(II) chloride in dichloromethane T=-25°C; 1 h; ruthenium(II) catalyzed reaction of 1,4-endoperoxide; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 104, # 7 p. 2024 - 2025
反应条件
tetrabutyl ammonium fluoride; triethylamine in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Curran, Timothy T.; Hay, David A.; Koegel, Christopher P.; Evans, Jonathan C.
Tetrahedron, 1997 , vol. 53, # 6 p. 1983 - 2004
反应条件
barium dihydroxide in methanol; water 4 h; Ambient temperature;
参考文献
Nara, M; Terashima, S.; Yamada, S.
Tetrahedron, 1980 , vol. 36, p. 3161 - 3170
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium tert-butylate; triphenylphosphine in tetrahydrofuran T=20°C; Inert atmosphereReflux; regioselective reaction;
参考文献
Tetrahedron Letters, , vol. 51, # 10 p. 1407 - 1410
参考文献
Angewandte Chemie, , vol. 68, p. 248
