顺式-7,8-环氧-2-甲基十八烷合成路线 （共 28 条）
反应条件
triphenylphosphine hydroiodide; triphenylphospine diiodide in hexane; benzene 1.) 24 h, 0 deg C, 2.) 24 h, room temp.;
参考文献
Sonnet, Philip E.
Synthesis, 1980 , # 10 p. 828 - 830
反应条件
bis(cyclopentadienyl)titanium dichloride; magnesium in tetrahydrofuran 12 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Schobert, Rainer
Angewandte Chemie, 1988 , vol. 100, # 6 p. 869 - 871
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane
Title compound not separated from byproducts;
参考文献
Chan, T. H.; Koumaglo, K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 109 - 120
反应条件
3-chloro-benzenecarboperoxoic acid
参考文献
Brown; Basavaiah
Synthesis, 1983 , vol. No. 4, p. 283 - 284
反应条件
1: H2 / Lindlar / ethanol / Ambient temperature
2: m-chloroperoxybenzoic acid / CH2Cl2 / 0 °C
View Scheme
参考文献
Jonas, Jaroslav; Slanina, Pavel; Humpa, Otakar; Mazal, Ctibor
Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 857 - 859
反应条件
1: 1) Li, liq.NH3, Fe(NO3)3 / 1) THF, 1 h, 2) THF, 2 h
2: 95 percent / H2 / Lindlar's catalyst / hexane
3: 90 percent / NEt3 / CH2Cl2 / 0 °C
4: 1) Mg, 2) HMPA / 1) THF, 2) THF, r.t., overnight
5: 60 percent / m-chloroperbenzoic acid / CH2Cl2 / 1) 0 deg C, 45 min, 2) r.t., 30 min
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 860 - 861
反应条件
3-chloro-benzenecarboperoxoic acid
参考文献
Koumaglo, K.; Chan, T. H.
Tetrahedron Letters, 1984 , vol. 25, # 7 p. 717 - 720
反应条件
1: 1.) MeLi, 2.) HMPA, 3.) CSA
2: 49 percent / Et3N / CH2Cl2 / 0.25 h / 0 °C
3: 95 percent / H2 / 10percent Pd/C / tetrahydrofuran / 24 h / 760 Torr
4: 1.) MsCl, Et3N, 2.) TBAF / 1.) CH2Cl2, 0 deg C, 30 min, 2.) CH2Cl2, THF, RT, 15 h
View Scheme
参考文献
Friesen; Giroux
Canadian Journal of Chemistry, 1994 , vol. 72, # 8 p. 1857 - 1865
反应条件
1: Na / 1) NH3(l); 2) DMF, 1 h
2: n-BuLi / 1) diglyme, 80-90 deg C, 6 h; 2) 130-140 deg C, 60 h
3: H2 / Lindlar / ethanol / Ambient temperature
4: m-chloroperoxybenzoic acid / CH2Cl2 / 0 °C
View Scheme
参考文献
Jonas, Jaroslav; Slanina, Pavel; Humpa, Otakar; Mazal, Ctibor
Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 857 - 859
反应条件
1: 95 percent / H2 / Lindlar's catalyst / hexane
2: 90 percent / NEt3 / CH2Cl2 / 0 °C
3: 1) Mg, 2) HMPA / 1) THF, 2) THF, r.t., overnight
4: 60 percent / m-chloroperbenzoic acid / CH2Cl2 / 1) 0 deg C, 45 min, 2) r.t., 30 min
View Scheme
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 860 - 861
