(η5-C5H5)Fe(CO)2Me in N,N-dimethyl-formamide Bu2GeH2 was treated with Et3SiH (2 equiv.) in DMF in presence of Fe catalyst at 100°C for 24 h in sealed tube;
dibenzoyl peroxide in benzene
hydrogermane (0.51 mmol), dibenzoyl peroxide (0.02 mmol) and benzene (50.64 mmol) heated at 80°C for 15 h; isolated by preparative GLC;
参考文献
Mochida, Kunio; Miyagawa, Isoo
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1875 - 1876
dibenzoyl peroxide in benzene
hydrogermane (0.77 mmol), dibenzoyl peroxide (0.07 mmol) and benzene (77.71 mmol) heated at 80°C for 15 h; isolated by preparative GLC;
参考文献
Mochida, Kunio; Miyagawa, Isoo
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 6 p. 1875 - 1876
in benzene-d6
(Ar); std. Schlenk technique; Si compd. (3 equiv.) was added to soln. ofPt complex (1 equiv.) in C6D6 at room temp. in NMR tube; reacted for 46 h; NMR monitoring;
