Pd(P(t-Bu)2Me)2; potassium tert-butylate; N,N-dicyclohexylamine in 1,4-dioxane T=80°C; 8 h; Inert atmosphere;

Pd(P(t-Bu)2Me)2; potassium tert-butylate; N,N-dicyclohexylamine in 1,4-dioxane T=20°C; 24 h; Inert atmosphere; Kinetics; Concentration;

1.1: sodium hydride / tetrahydrofuran / 0 °C / |Inert atmosphere 1.2: 20 °C / |Inert atmosphere 2.1: 10 Pd/C; hydrogen / methanol / 18 h / 20 °C / 760.05 Torr 3.1: lithium aluminium tetrahydride / diethyl ether / 0 - 20 h 4.1: 4-(N,N-dimethlyamino)pyridine; triethylamine / dichloromethane / 0 - 20 °C / |Inert atmosphere 5.1: Pd(P(t-Bu)2Me)2; potassium tert-butylate; N,N-dicyclohexylamine / 1,4-dioxane / 8 h / 80 °C / |Inert atmosphere View Scheme

diethyl ether