n-辛基-β-D-吡喃葡萄糖苷合成路线 （共 30 条）
反应条件
1: 90 percent / glacial acetic acid; hydrobromic acid / 2 h / 30 °C 2: 9.1 g / lithium carbonate / CH2Cl2 / 18 h / 30 °C 3: 67 percent / sodium methoxide / methanol / 24 h / 20 °C View Scheme
参考文献
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, , vol. 45, # 2 p. 461 - 465
反应条件
1: 100 percent / triphenylphosphane; imidazole; iodine / tetrahydrofuran / 0.5 h / 20 °C 2: 92 percent / NaBH4 / dimethylsulfoxide / 1 h / 20 °C 3: 89 percent / potassium carbonate / methanol / 0.42 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 15, # 10 p. 1623 - 1629
反应条件
1: 92 percent / NaBH4 / dimethylsulfoxide / 1 h / 20 °C 2: 89 percent / potassium carbonate / methanol / 0.42 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 15, # 10 p. 1623 - 1629
反应条件
1: 80 percent / lipase Amano P / H2O; diisopropyl ether / 22 h / 33 °C 2: 100 percent / triphenylphosphane; imidazole; iodine / tetrahydrofuran / 0.5 h / 20 °C 3: 92 percent / NaBH4 / dimethylsulfoxide / 1 h / 20 °C 4: 89 percent / potassium carbonate / methanol / 0.42 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 15, # 10 p. 1623 - 1629
反应条件
citrate buffer; Aerosol-OT; β-glucosidase in octane T=20°C; pH=5.5; 120 h;
参考文献
Kouptsova; Klyachko; Levashov
Russian Journal of Bioorganic Chemistry, 2001 , vol. 27, # 6 p. 380 - 384
反应条件
1: SnCl4; 4A molecular sieves / CH2Cl2 / 4 h / 20 °C 2: MeONa / methanol / Heating View Scheme
参考文献
Helvetica Chimica Acta, , vol. 84, # 8 p. 2243 - 2289
反应条件
C9H11N5*C2HF6NO4S2 in water T=80°C; 24 h; Reagent/catalyst; Overall yield = 14 percent; stereoselective reaction;
参考文献
Carbohydrate Research, , vol. 381, p. 12 - 18
反应条件
1: 9.1 g / lithium carbonate / CH2Cl2 / 18 h / 30 °C 2: 67 percent / sodium methoxide / methanol / 24 h / 20 °C View Scheme
参考文献
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, , vol. 45, # 2 p. 461 - 465
反应条件
in water T=30°C; 48 h; β-glucosidase from Trichoderma viride; Yield given;
参考文献
Agricultural and Biological Chemistry, , vol. 55, # 6 p. 1679 - 1681
反应条件
phosphate buffer; β-glucosidase T=30°C; pH=5; 17 h;
参考文献
Kurashima, Katsumi; Fujii, Mikio; Ida, Yoshiteru; Akita, Hiroyuki
Chemical and Pharmaceutical Bulletin, 2004 , vol. 52, # 2 p. 270 - 275
