(1S,2S)-(-)-1,2-二苯基乙二胺合成路线 (共 32 条)
反应条件
1: 81 percent / LiN3 / dimethylformamide / 120 °C 2: pyridine 3: LiN3 / dimethylformamide / 120 °C 4: H2 / 10percent Pd/C / ethyl acetate / 38000 Torr View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 2 p. 95 - 97
反应条件
1: pyridine 2: LiN3 / dimethylformamide / 120 °C 3: H2 / 10percent Pd/C / ethyl acetate / 38000 Torr View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 2 p. 95 - 97
反应条件
1: NaN3 / dimethylformamide 2: LiAlH4 / diethyl ether View Scheme
参考文献
Synthesis, , # 11 p. 1023 - 1024
反应条件
sodium in ethanol 0.166667 h; Heating; Yield given. Yields of byproduct given;
参考文献
Russian Chemical Bulletin, , vol. 46, # 1 p. 96 - 100
反应条件
1.1: NaOAc 1.2: 95 percent / HCl / H2O 2.1: 49 percent / HBr; AcOH View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 17, # 20 p. 2935 - 2937
反应条件
via co-crystalization with N*-chiral dimeric ortho-palladated matrix SCRN-L>PdCl>2 L=2-<1-(N-isopropylamino)ethyl>phenyl-CN;
参考文献
Tetrahedron Asymmetry, , vol. 9, # 11 p. 1917 - 1921
反应条件
1: (i) NaN3, Fe2(SO4)3, (ii) H2O2, (iii) Sn, aq. HCl View Scheme
参考文献
Gazzetta Chimica Italiana, , vol. 102, p. 855 - 892
反应条件
in chloroform-d1 Equilibrium constant;
参考文献
Journal of the American Chemical Society, , vol. 132, # 9 p. 2961 - 2967
反应条件
hydrogen; platinum(IV) oxide
参考文献
Denmark, Scott E.; Su, Xiping; Nishigaichi, Yutaka; Coe, Diane M.; Wong, Ken-Tsung; Winter, Stephen B. D.; Choi, Jun Young
Journal of Organic Chemistry, 1999 , vol. 64, # 6 p. 1958 - 1967
反应条件
triethylamine in dichloromethane T=5 - 20°C;
参考文献
NATIONAL UNIVERSITY OF SINGAPORE; TAN, Choon Hong; HUANG, Kuo-Wei; MA, Ting; FU, Xiao
Patent: WO2012/57709 A1, 2012 ;
Location in patent: Page/Page column 8-9 ;