2-氯-6-甲氧基苯甲醛合成路线 （共 12 条）
反应条件
Dess-Martin periodane in dichloromethane T=0 - 20°C; 3 h;
参考文献
WO2009/62285 A1, ;
Page/Page column 72-73 ;
反应条件
sodium hydroxide in methanol; hexane; dichloromethane; water
反应条件
1: 1-chloro-3-methoxy-benzene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine; diisopropylamine in tetrahydrofuran T=-78°C; 1 h; Inert atmosphere; 2: N,N-dimethyl-formamide T=-78°C; 0.5 h; Inert atmosphere; regioselective reaction;
参考文献
Tetrahedron Letters, , vol. 54, # 45 p. 6053 - 6056
反应条件
1.1: 75 percent / ethanol / 24 h / 25 °C 2.1: tert-BuLi / diethyl ether; pentane / 7 h / -20 °C 2.2: (BrCl2C)2 / diethyl ether / -78 - 20 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 128, # 34 p. 11044 - 11053
反应条件
1: Ca(OH)2, Na2CO3 / H2O 2: OH- View Scheme
参考文献
Journal of Organic Chemistry, , vol. 29, p. 2693 - 2698
反应条件
sodium methylate 12 h; Heating;
参考文献
Gazzetta Chimica Italiana, , vol. 123, # 11 p. 617 - 622
参考文献
Journal of Organic Chemistry, , vol. 29, p. 2693 - 2698
反应条件
(i) Br2, (irradiation), (ii) (hydrolysis); Multistep reaction;
参考文献
Acta Chemica Scandinavica (1947-1973), , vol. 24, # 4 p. 1459 - 1460
反应条件
boron trifluoride diethyl etherate; boron tribromide; 2,3-dicyano-5,6-dichloro-p-benzoquinone Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Banfi, Stefano; Montanari, Fernando; Pozzi, Gianluca; Quici, Silvio
Gazzetta Chimica Italiana, 1993 , vol. 123, # 11 p. 617 - 622
反应条件
potassium permanganate
参考文献
Postmus,C. et al.
Journal of Organic Chemistry, 1964 , vol. 29, p. 2693 - 2698
