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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
29910-92-7
合成路线
(共 73 条)
4410-99-5
2-苯乙硫醇
+
60-12-8
苯乙醇
+
1207372-96-0
→
反应条件
29910-92-7
+
34372-24-2
+
54894-37-0
[(2-苯基乙氧基)甲基]苯
反应条件
PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=80°C; 15 h; Inert atmosphereDarkness;
参考文献
Jean, Mickael; Renault, Jacques; van de Weghe, Pierre; Asao, Naoki
Tetrahedron Letters, 2010 , vol. 51, # 2 p. 378 - 381
1201651-60-6
→
反应条件
29910-92-7
反应条件
PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate in benzene T=20°C; Inert atmosphere;
参考文献
Hashmi, A. Stephen K.; Lothschuetz, Christian; Doepp, Rene; Ackermann, Martin; De Buck Becker, Janosc; Rudolph, Matthias; Scholz, Christian; Rominger, Frank
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 1 p. 133 - 147
143-10-2
1-癸硫醇
+
1207372-98-2
→
反应条件
19313-57-6
+
29910-92-7
反应条件
PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate in 1,2-dichloro-ethane T=80°C; 15 h; Inert atmosphereDarkness;
参考文献
Jean, Mickael; Renault, Jacques; van de Weghe, Pierre; Asao, Naoki
Tetrahedron Letters, 2010 , vol. 51, # 2 p. 378 - 381
33577-99-0
2-乙炔苯甲酸甲酯
→
反应条件
29910-92-7
反应条件
1: 84 percent / PPh3; triethylamine / CuI; PdCl2(PPh3)2 / tetrahydrofuran / 4 h / 70 °C 2: 90 percent / potassium carbonate; water / gold(III) chloride / acetonitrile / 24 h / 50 °C View Scheme
参考文献
Marchal, Estelle; Uriac, Philippe; Legouin, Beatrice; Toupet, Loic; Weghe, Pierre van de
Tetrahedron, 2007 , vol. 63, # 40 p. 9979 - 9990
107793-07-7
→
反应条件
29910-92-7
反应条件
1: 97 percent / potasssium carbonate / methanol; ethanol 2: 84 percent / PPh3; triethylamine / CuI; PdCl2(PPh3)2 / tetrahydrofuran / 4 h / 70 °C 3: 90 percent / potassium carbonate; water / gold(III) chloride / acetonitrile / 24 h / 50 °C View Scheme
参考文献
Marchal, Estelle; Uriac, Philippe; Legouin, Beatrice; Toupet, Loic; Weghe, Pierre van de
Tetrahedron, 2007 , vol. 63, # 40 p. 9979 - 9990
130818-20-1
→
反应条件
1141496-45-8
+
29910-92-7
反应条件
copper(l) chloride in acetonitrile 2 h; Reflux;
参考文献
Chin, Ling-Yu; Lee, Chia-Ying; Lo, Yu-Hsiang; Wu, Ming-Jung
Journal of the Chinese Chemical Society, 2008 , vol. 55, # 3 p. 643 - 648
130818-20-1
→
反应条件
667897-47-4
+
29910-92-7
反应条件
copper(I) bromide in acetonitrile 2 h; Reflux;
参考文献
Chin, Ling-Yu; Lee, Chia-Ying; Lo, Yu-Hsiang; Wu, Ming-Jung
Journal of the Chinese Chemical Society, 2008 , vol. 55, # 3 p. 643 - 648
1207372-96-0
→
反应条件
29910-92-7
+
1357469-25-0
反应条件
PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate in dichloromethane T=20°C; Inert atmosphere;
参考文献
Hashmi, A. Stephen K.; Lothschuetz, Christian; Doepp, Rene; Ackermann, Martin; De Buck Becker, Janosc; Rudolph, Matthias; Scholz, Christian; Rominger, Frank
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 1 p. 133 - 147
1357469-13-6
→
反应条件
29910-92-7
+
1357469-26-1
反应条件
tris-(dibenzylideneacetone)dipalladium(0); PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate in dichloromethane T=20°C; Inert atmosphere;
参考文献
Hashmi, A. Stephen K.; Lothschuetz, Christian; Doepp, Rene; Ackermann, Martin; De Buck Becker, Janosc; Rudolph, Matthias; Scholz, Christian; Rominger, Frank
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 1 p. 133 - 147
88-67-5
邻碘苯甲酸
+
768-60-5
4-乙炔基苯甲醚
→
反应条件
71126-50-6
+
29910-92-7
反应条件
copper(l) iodide; caesium carbonate in dimethyl sulfoxide T=25°C; 12 h; Overall yield = 68 percent; Overall yield = 343 mg; regioselective reaction;
参考文献
Kumar, Manian Rajesh; Irudayanathan, Francis Mariaraj; Moon, Joong Ho; Lee, Sunwoo
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3221 - 3230
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