1,5-二氮杂双环[4.3.0]壬-5-烯合成路线 （共 18 条）
反应条件
1: With oxalyl dichloride in dichloromethane T=0 - 25°C; 25 h; 2: With amberlite IRA 400 (OH(-)) in methanol
参考文献
Kumagai, Naoya; Matsunaga, Shigeki; Shibasaki, Masakatsu
Angewandte Chemie - International Edition, 2004 , vol. 43, # 4 p. 478 - 482
参考文献
Mitsubishi Petrochemical Co., Ltd.
Patent: US4892944 A1, 1990 ;
反应条件
ammonia; cobalt T=100°C; P=147102 Torr; Hydrogenation;
参考文献
Justus Liebigs Annalen der Chemie, , vol. 596, p. 1,211
反应条件
1: acetonitrile 2: Raney cobalt; ethanolic NH3 / 100 °C / 147102 Torr / Hydrogenation View Scheme
参考文献
Justus Liebigs Annalen der Chemie, , vol. 596, p. 1,211
反应条件
1: 150 °C 2: Raney cobalt; ethanolic NH3 / 100 °C / 147102 Torr / Hydrogenation View Scheme
参考文献
Justus Liebigs Annalen der Chemie, , vol. 596, p. 1,211
参考文献
Journal of Organic Chemistry, , vol. 63, # 23 p. 8599 - 8603
反应条件
phosphorus tribromide; sodium hydrogencarbonate in hexane; dimethyl sulfoxide
参考文献
Firmenich S.A.
Patent: US3960977 A1, 1976 ;
反应条件
in dimethyl sulfoxide
参考文献
Firmenich S.A.
Patent: US3960977 A1, 1976 ;
反应条件
1: 85 percent / diisobutylaluminium hydride (DIBAH) / toluene / Heating 2: 73 percent / toluene; H2O / 2 h / Heating View Scheme
参考文献
Alder, Roger W.; Heilbronner, Edgar; Honegger, Evi; McEwen, Alan B.; Moss, Richard E.; Olefirowicz, Edward; Petillo, Peter A.; Sessions, Richard B.; Weisman, Gary R.; White, Jonathan M.; Yang, Zhong-Zhi
Journal of the American Chemical Society, 1993 , vol. 115, # 15 p. 6580 - 6591
反应条件
1: 1.) LiAlH4, 2.) 0.1 M NaOH / 1.) diethyl ether, reflux, 2 h, 2.) 25 deg C, 10 min 2: 0.20 g / aq. HCl, NaBH4 / H2O / 16 h / 23 °C / pH 7 View Scheme
参考文献
Brandaenge, Svante; Eriksson, Lars-Hakan; Rodriguez, Benito
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1984 , vol. 38, # 6 p. 526 - 528
