(1,3-双-(2,4,6-三甲基苯基)-2-咪唑烷亚基)二氯(邻异丙氧基苯亚甲基)合钌合成路线 （共 7 条）
反应条件
in toluene T=65°C; 4 h;
参考文献
Winde, Roland; Doppiu, Angelino; Woerner, Eileen; Rivas-Nass, Andreas; Karch, Ralf; Slugovc, Christian; Schinagl, Christina
Patent: US2012/101279 A1, 2012 ;
Location in patent: Page/Page column 5 ;
反应条件
potassium 2-methyl-2-butoxide in hexane; toluene soln. of K compd. in toluene was added to suspn. of imidazolium salt in hexane under Ar; mixt. was stirred at room temp. for 1 h under Ar; solidRu complex was added; refluxed for 2 h under Ar; cooled to room temp.; solid CuCl added; refluxed for 2 h; evapd.; redisoolved in EtOAc; filtered through Celite; concd. (vac.); dissolved in CH2Cl2/MeOH (1/10, ambient temp.); concd. (vac.); filtered; washed (MeOH); dried (vac.);
参考文献
Bieniek, Michal; Michrowska, Anna; Gulajski, LUkasz; Grela, Karol
Organometallics, 2007 , vol. 26, # 4 p. 1096 - 1099
反应条件
in CD2Cl2 Kinetics; 243 K; NMR;
参考文献
Journal of the American Chemical Society, , vol. 132, # 8 p. 2784 - 2794
反应条件
1: not given 2: not given View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 43, # 45 p. 6161 - 6165
反应条件
CuCl in toluene dissolvingRue complex in toluene, addn. of CuCl and CH2CHC6H4OC3H7, stirring at 40°C; Leuthaeusser, S. et al. Chem. - Eur. J. 2007, 13, 7195; Leuthaeusser, S. et al. Chem. - Eur. J. 2008, 14, 5465;
参考文献
Organometallics, , vol. 29, # 19 p. 4339 - 4345
反应条件
in dichloromethane-d2 12 h; Inert atmosphereUV-irradiation;
参考文献
Khalimon, Andrey Y.; Leitao, Erin M.; Piers, Warren E.
Organometallics, 2012 , vol. 31, # 15 p. 5634 - 5637,4
反应条件
in benzene-d6 byproducts: picolinic acid; react. of Ru complexes with HCl and CH3CHCHC6H4O(CH(CH3)2) at 50°C;
参考文献
Journal of Organometallic Chemistry, , vol. 695, # 14 p. 1831 - 1837
