(Z)-2-溴-2-丁烯合成路线 （共 36 条）
反应条件
N,N,N',N,-tetramethylethylenediamine; hydrogen; di-(1-adamantyl)-n-butylphosphine; palladium diacetate in toluene T=100°C; P=5625.56 Torr; 16 h;
参考文献
Brennfuehrer, Anne; Neumann, Helfried; Klaus, Stefan; Riermeier, Thomas; Almena, Juan; Beller, Matthias
Tetrahedron, 2007 , vol. 63, # 27 p. 6252 - 6258
参考文献
v.Hoessle
Journal fuer Praktische Chemie (Leipzig), 1894 , vol. <2>49, p. 405
参考文献
Wislicenus; Pueckert; Schmidt
Justus Liebigs Annalen der Chemie, 1900 , vol. 313, p. 222
反应条件
potassium hydroxide; hydrogen in water T=45°C; 1.66667 h; Yield given. Yields of byproduct given;
参考文献
Funabiki, Takuzo; Hosomi, Hiroaki; Yoshida, Satohiro; Tarama, Kimio
Journal of the American Chemical Society, 1982 , vol. 104, # 6 p. 1560 - 1568
反应条件
NiBr2(PPh3)2; triphenylphosphine; zinc in N,N-dimethyl-formamide T=40°C; 8 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Sakakibara, Yasumasa; Enami, Hiroji; Ogawa, Hiroshi; Fujimoto, Shinpei; Kato, Hiroyuki; et al.
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 11 p. 3137 - 3144
反应条件
NiBr2(PPh3)2; triphenylphosphine; zinc in N,N-dimethyl-formamide T=30°C; 8 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Sakakibara, Yasumasa; Enami, Hiroji; Ogawa, Hiroshi; Fujimoto, Shinpei; Kato, Hiroyuki; et al.
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 11 p. 3137 - 3144
反应条件
pyridine; N,N'-dimethyl-N,N'-propyleneurea; 4,4'-dimethoxy-2,2'-bipyridine; NiI2*3.5H2O; sodium iodide; zinc T=20 - 60°C; 20 h; chemoselective reaction;
参考文献
Everson, Daniel A.; Jones, Brittany A.; Weix, Daniel J.
Journal of the American Chemical Society, 2012 , vol. 134, # 14 p. 6146 - 6159
反应条件
magnesium 1.) THF, 45-50 deg C, 1h, 2.) room temp., overnight; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Parr, William J. E.
Journal of Chemical Research, Miniprint, 1981 , # 11 p. 4101 - 4130
反应条件
Gleichgewicht bei der Einwirkung von Sonnenlicht;
参考文献
Dreiding; Pratt
Journal of the American Chemical Society, 1954 , vol. 76, p. 1902,1903,1904
反应条件
calcium hydroxide powder; methyl iodide; dicobalt octacarbonyl in 1,4-dioxane; water T=20°C; P=760 Torr; 20 h;
参考文献
Miura, Masahiro; Okuro, Kazumi; Hattori, Ayako; Nomura, Masakatsu
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 73 - 76
