N-十二烷基-N-甲基苯胺合成路线 (共 5 条)
反应条件
potassium carbonate in N,N-dimethyl-formamide T=80°C; 17 h;
参考文献
Markovitsi, Dimitra; Jallabert, Colette; Strzelecka, Helena; Veber, Michele
Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 16 p. 2819 - 2822
反应条件
1: dodec-1-ene With AgNO2; Pd(PhCN)2Cl2; CuCl2·2H2O; oxygen in nitromethane; tert-butyl alcohol T=20°C; Wacker Oxidation; 2: N-methylaniline With formic acid/triethylamine complex 5:2; chloro-(pentamethylcyclopentadienyl)-{5-methoxy-2-{1-[(4-methoxyphenyl)imino-N]ethyl}phenyl-C}-iridium(lll) in nitromethane; tert-butyl alcohol T=85°C; Inert atmosphere; chemoselective reaction;
参考文献
Bronner, Sarah M.; Grubbs, Robert H.
Chemical Science, 2013 , vol. 5, # 1 p. 101 - 106
反应条件
Fuller's Earth T=300°C; P=33097.9 Torr;
参考文献
I.G. Farbenind.
Patent: DE611283 , 1933 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 21, p. 203
反应条件
copper-aluminium oxide catalyst T=180°C; P=147102 Torr; Hydrogenation;
参考文献
I.G. Farbenind.
Patent: DE650664 , 1935 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 24, p. 136
反应条件
caesium carbonate in N,N-dimethyl-formamide
参考文献
Hong, Soo Yeon; Jun, Hyunsook; Yoon, Seung Soo; Kang, Chulhun; Suh, Myungkoo
Chemistry Letters, 2004 , vol. 33, # 3 p. 318 - 319