4-(羟甲基)苯硼酸频哪醇酯合成路线 （共 16 条）
反应条件
[Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2; sodium carbonate; bis[2-(diphenylphosphino)phenyl] ether in anhydrous xylene T=155°C; 24 h; Inert atmosphereReflux;
参考文献
Ma, Winson M. J.; James, Tony D.; Williams, Jonathan M. J.
Organic Letters, 2013 , vol. 15, # 18 p. 4850 - 4853
反应条件
carbon tetrabromide; triphenylphosphine in tetrahydrofuran T=20°C; 4 h; Cooling with ice;
参考文献
PROMEGA CORPORATION; KLAUBERT, Dieter; SHULTZ, John; UNCH, James; VALLEY, Michael P.; WANG, Hui; ZHOU, Wenhui
Patent: WO2013/25885 A1, 2013 ;
Location in patent: Paragraph 0086 ;
反应条件
1: N-ethyl-N,N-diisopropylamine / dichloromethane / 3 h / 0 °C / |Inert atmosphere 2: potassium carbonate / N,N-dimethyl-formamide / 72 h / 20 °C 3: hydrazine hydrate / tetrahydrofuran / 12 h / |Reflux View Scheme
参考文献
Molecules, , vol. 18, # 10 p. 12346 - 12367
反应条件
1: N-ethyl-N,N-diisopropylamine / dichloromethane / 3 h / 0 °C / |Inert atmosphere 2: potassium carbonate / N,N-dimethyl-formamide / 72 h / 20 °C View Scheme
参考文献
Chung, Sheng-Hsuan; Lin, Ting-Ju; Hu, Qian-Yu; Tsai, Chia-Hua; Pan, Po-Shen
Molecules, 2013 , vol. 18, # 10 p. 12346 - 12367
反应条件
copper(I) oxide; 1,10-phenanthroline; potassium iodide in methanol; water T=80°C; 1 h; High pressure;
参考文献
Partridge, Benjamin M.; Hartwig, John F.
Organic Letters, 2013 , vol. 15, # 1 p. 140 - 143
反应条件
1: sodium iodide; chloro-trimethyl-silane / acetonitrile / 12 h / 0 - 20 °C
2: potassium carbonate / N,N-dimethyl-formamide / 12 h / 0 - 35 °C
3: toluene-4-sulfonic acid / methanol / 2.5 h / 30 °C
4: triethylamine / dichloromethane / 12 h / 0 - 20 °C
5: dihydrogen peroxide / water-d2; acetonitrile-D3 / 60 °C
View Scheme
参考文献
Song, Cheng-Cheng; Ji, Ran; Du, Fu-Sheng; Li, Zi-Chen
Macromolecules, 2013 , vol. 46, # 21 p. 8416 - 8425
