2,5-二甲基-1,4-亚苯基二硼酸频那醇酯合成路线 （共 5 条）
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate in N,N-dimethyl-formamide T=85°C; 48 h; Inert atmosphere;
参考文献
UWM RESEARCH FOUNDATION, INC.; Peng, Xiaohua; Kuang, Yunyan; Cao, Sheng; Chen, Wenbing; Wang, Yibin
Patent: US2013/45949 A1, 2013 ;
Location in patent: Paragraph 0408 ;
反应条件
bis-triphenylphosphine-palladium(II) chloride; 2-azidoethanol in toluene T=80°C; Condensation; 12 h;
参考文献
Iovine; Kellett; Redmore; Therien
Journal of the American Chemical Society, 2000 , vol. 122, # 36 p. 8717 - 8727
反应条件
tert.-butyl lithium in tetrahydrofuran T=-78°C; 1 h;
参考文献
Park, Young-Il; Lee, Joong Suk; Kim, Beom Joon; Kim, Beomjin; Lee, Jaehyun; Kim, Do Hwan; Oh, Se-Young; Cho, Jeong Ho; Park, Jong-Wook
Chemistry of Materials, 2011 , vol. 23, # 17 p. 4038 - 4044
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran
Suzuki coupling; 6 h; Heating;
参考文献
Vak, Doojin; Lim, Bogyu; Lee, Soo-Hyoung; Kim, Dong-Yu
Organic Letters, 2005 , vol. 7, # 19 p. 4229 - 4232
反应条件
1: 93 percent / Pd(PPh3)4; aq. K2CO3 / tetrahydrofuran / 6 h / Heating
2: aq. KMnO4; pyridine / 6 h / Heating
3: H2SO4 / 12 h / 80 °C
View Scheme
参考文献
Vak, Doojin; Lim, Bogyu; Lee, Soo-Hyoung; Kim, Dong-Yu
Organic Letters, 2005 , vol. 7, # 19 p. 4229 - 4232
