2,4,6-三乙基环硼氧烷合成路线 （共 34 条）
参考文献
Gmelin Handbook: B: B-Verb.13, 4.7.2, page 180 - 189
反应条件
heating of the diborane and the phosphinoylborane to 120°C, stirring for 2 h, cooling to 20°C, all steps under exclusion of air and moisture; monitored by NMR;
参考文献
Koester, Roland; Schuessler, Wilhelm; Synoradzki, Ludwik
Chemische Berichte, 1987 , vol. 120, p. 1105 - 1116
参考文献
Koester, Roland; Angermund, Klaus; Serwatowski, Janusz; Sporzynski, Andrzej
Chemische Berichte, 1986 , vol. 119, # 4 p. 1301 - 1314
反应条件
ration of the starting phosphine oxide to diborane (1:2.5), under exclusion of air and moisture;
参考文献
Koester, Roland; Tsay, Yi-Hung; Synoradzki, Ludwik
Chemische Berichte, 1987 , vol. 120, p. 1117 - 1124
参考文献
McCusker et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5179
反应条件
in paraffin Product distribution / selectivity;
参考文献
EP1903047 A1, ;
Page/Page column 7 ;
反应条件
in toluene boroxine was added dropwise under Ar to an agitated soln. of(C2H5AlCl2)2 in toluene at -78°C and the mixt. allowed to warm slowly up to 20°C;; removal of volatiles (1 Torr/20 °C), sublimation at 0.001 Torr/60 °C;;
参考文献
Chemische Berichte, , vol. 119, # 4 p. 1301 - 1314
反应条件
Heating; Product distribution; Further Variations:Reaction partners;
参考文献
Sonnenschein, Mark F.; Webb, Steven P.; Kastl, Patrick E.; Arriola, Daniel J.; Wendt, Benjamin L.; Harrington, Daniel R.; Rondan, Nelson G.
Macromolecules, 2004 , vol. 37, # 21 p. 7974 - 7978
反应条件
in hexane
boroxine was added under Ar to an agitated suspension of (AlBr3)2 in hexane;; dibromethylborane in hexane was filtered off from the crude prod., the latter was dried in vac. and recrystd. from hexane; elem. anal.;;
参考文献
Koester, Roland; Angermund, Klaus; Serwatowski, Janusz; Sporzynski, Andrzej
Chemische Berichte, 1986 , vol. 119, # 4 p. 1301 - 1314
参考文献
Michailow; Kosminskaja
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959 , p. 1866;engl.Ausg.S.1785
