5-乙烯基双环[2.2.1]庚-2-烯合成路线 (共 26 条)
反应条件
T=206°C; Cope Rearrangement; P=10343.2 Torr; 0.666667 h; Pyrolysis; Product distribution / selectivity;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 10; 15-16 ;
反应条件
T=165 - 210°C; Cope Rearrangement; 3.36 - 66.72 h; Pyrolysis; Kinetics;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 13 ;
反应条件
T=150°C; Cope Rearrangement; 69.6333 h; Pyrolysis; Product distribution / selectivity;
参考文献
US2009/54714 A1, ;
Page/Page column 13-14 ;
反应条件
T=141 - 166°C; Cope Rearrangement; 216 h; Pyrolysis; Product distribution / selectivity;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 12 ;
反应条件
1: 1.) NaBH4, BF3*O(C2H5)2, 2.)aq. NaOH, 30 percent aq. H2O2 / 1.) THF, RT, 3 h, 2.) THF/H2O, 40 deg C, 3 h 2: 42.1 percent / iodine, potassium iodide, NaHCO3 / dioxane; H2O / 1 h / Ambient temperature 3: 48.7 percent / pyridine / Ambient temperature 4: 55 percent / pyridine / 12 h / Heating View Scheme
参考文献
Inoue, Yoshiharu
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, p. 1954 - 1956
反应条件
T=141 - 166°C; Cope Rearrangement; 216 h; Pyrolysis; Product distribution / selectivity;
参考文献
US2009/54714 A1, ;
Page/Page column 12 ;
反应条件
tert.-butylhydroperoxide; silica-supported polyamidoamine dendrimer G1-C6-Pd(dba) in various solvent(s) T=55°C; 24 h;
参考文献
Zweni, Pumza P.; Alper, Howard
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 7 p. 849 - 854
反应条件
T=141 - 166°C; Cope Rearrangement; 216 h; Pyrolysis; Product distribution / selectivity;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 12 ;
反应条件
T=141 - 165°C; Cope Rearrangement; 216 h; Pyrolysis; Product distribution / selectivity;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 14 - 15 ;
反应条件
T=206°C; Cope Rearrangement; P=10343.2 Torr; 0.666667 h; Pyrolysis; Product distribution / selectivity;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 10; 15-16 ;