(E)-2-甲基-2-丁烯腈合成路线 （共 10 条）
反应条件
C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite; zinc(II) chloride Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73172 A1, 2005 ;
Location in patent: Page/Page column title page; 37-40; sheet 1 ;
反应条件
1: With trichlorophosphate T=90 - 110°C; 2: in water T=0°C;
参考文献
US2011/46170 A1, ;
Page/Page column 19 ;
反应条件
potassium phosphate buffer; Escherichia coli SS1001 cells in water T=35°C; 2.5 h;
参考文献
Hann, Eugenia C.; Sigmund, Amy E.; Fager, Susan K.; Cooling, Frederick B.; Gavagan, John E.; Bramucci, Michael G.; Chauhan, Sarita; Payne, Mark S.; DiCosimo, Robert
Tetrahedron, 2004 , vol. 60, # 3 p. 577 - 581
反应条件
water; E. coli SS1001 Cells (ATCC PTA-1177) T=25 - 35°C; pH=7; 6 - 23 h; Enzymatic reactionAqueous phosphate buffer; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2004/101513 A2, 2004 ;
Location in patent: Page 24-26 ;
反应条件
C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite; zinc(II) chloride Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73172 A1, 2005 ;
Location in patent: Page/Page column title page; 37-40; sheet 1 ;
反应条件
C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite; zinc(II) chloride Product distribution / selectivity;
参考文献
WO2005/73172 A1, ;
Page/Page column title page; 33-36; sheet 1 ;
反应条件
C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite; zinc(II) chloride Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73172 A1, 2005 ;
Location in patent: Page/Page column title page; 37-40; sheet 1 ;
反应条件
1: trichlorophosphate / 15 h / 90 - 100 °C 2: tetrahydrofuran / 2 h / 0 °C 3: pyridinium chlorochromate / dichloromethane / 5 h / 20 °C View Scheme
参考文献
SYNGENTA PARTICIPATIONS AG; CASSAYRE, Jerome Yves; EL QACEMI, Myriem; LUKSCH, Torsten; RENOLD, Peter
Patent: WO2012/156400 A1, 2012 ;
反应条件
1.1: trichlorophosphate / 90 - 110 °C
1.2: 0 °C
2.1: formic acid; dihydrogen peroxide / water / 15 h / 0 °C
View Scheme
参考文献
Bolli, Martin; Lescop, Gyrille; Mathys, Boris; Mueller, Claus; Nayler, Oliver; Steiner, Beat
Patent: US2011/46170 A1, 2011 ;
反应条件
tetrabutylammomium bromide; sodium in toluene
参考文献
Consortium fur elektrochemische Industrie GmbH
Patent: US4625046 A1, 1986 ;
