1: With 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; iodine in dichloromethane T=20°C; 2 h; Inert atmosphere; 2: With ammonia; iodine in dichloromethane; water T=20°C; 2 h; Inert atmosphere;
cation exchange resin BioRad AG 50W-X12 (H+); sodium iodide in acetonitrile T=75°C; further solvent: THF, DMSO; Product distribution;
参考文献
Barrio, Jorge R.; Satyamurthy, Nagichettiar; Ku, Hao; Phelps, Michael E.
Journal of the Chemical Society, Chemical Communications, 1983 , # 8 p. 443 - 444
3-chloroprop-1-ene; trifluoroacetic acid; zinc; Co(2,2'-bipyridine)Br2 in pyridine; N-dodecane; acetonitrile T=50°C; 0.5 h; Title compound not separated from byproducts;
