2,2-二氯-1,1,1-三氟乙烷合成路线 （共 115 条）
反应条件
hydrogen fluoride; chlorine; SbF5 T=126 - 148°C; P=17251.7 - 20252 Torr; 7.1 h;
参考文献
WO2004/46071 A1, ;
Page column 13-14 ;
反应条件
hydrogen fluoride; chromium-based fluorination catalyst T=300 - 320°C; P=3000.3 Torr;
参考文献
US2004/15022 A1, ;
Page 5; 7 ;
反应条件
hydrogen fluoride; SbF3; SbF5 T=129 - 143°C; P=17626.8 - 19502 Torr; 4.1 h;
参考文献
WO2004/46071 A1, ;
Page column 6-7 ;
反应条件
hydrogen fluoride; SbF3; SbF5 T=125 - 139°C; P=16351.6 - 18376.8 Torr; 3.7 h;
参考文献
WO2004/46071 A1, ;
Page column 10 ;
反应条件
(NH4)2S2O8; ammonium formate in N,N-dimethyl-formamide T=30 - 40°C;
参考文献
Hu, Chang-Ming; Tu, Ming-Hu
Journal of Fluorine Chemistry, 1991 , vol. 55, # 1 p. 105 - 108
反应条件
hydrogen; Ru/AlF3 T=130 - 150°C; 2 - 24 h;
参考文献
US6348634 B1, ;
Page column 3-4; 5 ;
反应条件
hydrogen; 5 wt Ru/carbon T=100 - 130°C; 20 h;
参考文献
US6348634 B1, ;
Page column 4-5 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 90/10, 12-20 mesh, (1.68 to 0.84 mm) ), prepared from chromium (III) nitrate, cobalt (II) nitrate, ammonia, ammonia nitrate (400°C) T=200 - 425°C; 9.33333 h;
参考文献
WO2004/18396 A1, ;
Page 14 ;
反应条件
hydrogen fluoride Conversion of starting material;
参考文献
US2003/191350 A1, ;
Page/Page column 7-10 ;
反应条件
hydrogen fluoride; cobalt-substituted chromium oxide (Cr/Co 90/10, 12-20 mesh, (1.68 to 0.84 mm) ), prepared from chromium (III) nitrate, cobalt (II) nitrate, ammonia (400°C) T=200 - 425°C; 9.33333 h;
参考文献
WO2004/18396 A1, ;
Page 13-14 ;
