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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
30647-85-9
合成路线
(共 10 条)
1942-45-6
4-辛炔
→
反应条件
30647-85-9
反应条件
sulfuric acid; dihydrogen peroxide; tris(cetyl)pyridinium 12-tungstophosphate in ethanol; chloroform 3 h; Heating; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Sakaguchi, Satoshi; Watase, Seiji; Katayama, Yuji; Sakata, Yasuyuki; Nishiyama, Yutaka; Ishii, Yasutaka
Journal of Organic Chemistry, 1994 , vol. 59, # 19 p. 5681 - 5686
1942-45-6
4-辛炔
→
反应条件
30647-85-9
反应条件
peracetic acid
参考文献
Rodriguez, Jaime; Nieto, Rosa M.; Blanco, Maria; Valeriote, Frederick A.; Jimenez, Carlos; Crews, Phillip
Organic Letters, 2014 , vol. 16, # 2 p. 464 - 467
14850-23-8
反-4-辛烯
→
反应条件
30647-85-9
反应条件
2-hydroxy-1,3-isoindolinedione; sodium perchlorate in pyridine; acetonitrile Ambient temperatureelectrochemical oxidation, 1.5 F/mol;
参考文献
Masui, Masaichiro; Hosomi, Katsuko; Tsuchida, Keiichi; Ozaki, Shigeko
Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 11 p. 4798 - 4802
84053-60-1
→
反应条件
30647-85-9
+
142312-73-0
反应条件
N-bromosuccinmide in dichloromethane 1.5 h; Ambient temperature;
参考文献
Courtneidge, John L.; Bush, Melanie; Loh, Lay See
Tetrahedron, 1992 , vol. 48, # 18 p. 3835 - 3856
1942-45-6
4-辛炔
→
反应条件
30647-85-9
反应条件
HOF* CH3CN in chloroform T=0 - 20°C; Title compound not separated from byproducts.;
参考文献
Dayan; Ben-David; Rozen
Journal of Organic Chemistry, 2000 , vol. 65, # 25 p. 8816 - 8818
67-56-1
甲醇
+
1942-45-6
4-辛炔
→
反应条件
30647-85-9
+
22632-59-3
甲基2-丙基戊酸酯
反应条件
sulfuric acid; dihydrogen peroxide; tris(cetyl)pyridinium 12-tungstophosphate in chloroform 24 h; Heating; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Sakaguchi, Satoshi; Watase, Seiji; Katayama, Yuji; Sakata, Yasuyuki; Nishiyama, Yutaka; Ishii, Yasutaka
Journal of Organic Chemistry, 1994 , vol. 59, # 19 p. 5681 - 5686
1942-45-6
4-辛炔
→
反应条件
30647-85-9
+
5162-93-6
+
107-92-6
丁酸
反应条件
dihydrogen peroxide; tris(cetyl)pyridinium 12-tungstophosphate in chloroform 24 h; Heating;
参考文献
Ishii, Yasutaka; Sakata, Yasuyuki
Journal of Organic Chemistry, 1990 , vol. 55, # 21 p. 5545 - 5547
72755-70-5
→
反应条件
30647-85-9
+
142312-74-1
反应条件
tert-butylhypochlorite; silica gel in dichloromethane
参考文献
Courtneidge, John L.; Bush, Melanie; Loh, Lay See
Tetrahedron, 1992 , vol. 48, # 18 p. 3835 - 3856
1942-45-6
4-辛炔
→
反应条件
589-63-9
4-辛酮
+
5455-24-3
4,5-辛二酮
+
30647-85-9
+
107-92-6
丁酸
反应条件
dihydrogen peroxide; tris(cetylpyridinium) 12-molybdenophosph in water; 1,2-dichloro-ethane T=40°C; 13 h; other polyoxometalate catalysts, var. internal alkynes; Product distribution;
参考文献
Ballistreri, Francesco Paolo; Failla, Salvatore; Spina, Emanuela; Tomaselli, Gaetano Andrea
Journal of Organic Chemistry, 1989 , vol. 54, # 4 p. 947 - 949
7642-15-1
顺-4-辛烯
→
反应条件
30647-85-9
反应条件
1: 75 percent / 5,10,15,20-tetraphenyl-21H,23H-porphine (TPP), 2,6-di-tert-butyl-4-methylphenol (BHT), O2 / CH2Cl2 / 4 h / Ambient temperature; Irradiation 2: 7 percent / Bu-tert-OCl, silica gel / CH2Cl2 View Scheme
参考文献
Courtneidge, John L.; Bush, Melanie; Loh, Lay See
Tetrahedron, 1992 , vol. 48, # 18 p. 3835 - 3856