in acetic acid T=40°C; 1 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

in acetic acid T=40°C; 1 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

1: 6-fluorobenzolt;agt;pyrene With iodine; silver perchlorate in benzene Radical cation*AgI formation; 2: anhydrous tetramethylammonium acetate in water; acetonitrile Substitution;

1: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C 2: platinum (II) chloride / toluene / Heating 3: boron tribromide 4: bis-[(trifluoroacetoxy)iodo]benzene View Scheme

1.1: methanesulfonic acid / Heating 2.1: pyridine / dichloromethane / 20 °C 2.2: 20 °C / Cooling 3.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere 4.1: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C 5.1: platinum (II) chloride / toluene / Heating 6.1: boron tribromide 7.1: bis-[(trifluoroacetoxy)iodo]benzene View Scheme

1.1: pyridine / dichloromethane / 20 °C 1.2: 20 °C / Cooling 2.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere 3.1: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C 4.1: platinum (II) chloride / toluene / Heating 5.1: boron tribromide 6.1: bis-[(trifluoroacetoxy)iodo]benzene View Scheme

1: platinum (II) chloride / toluene / Heating 2: boron tribromide 3: bis-[(trifluoroacetoxy)iodo]benzene View Scheme

1.1: (1,2,3,4,5-pentaphenylferrocen-1'-yl)-di-tert-butylphosphine; bis(dibenzylideneacetone)-palladium(0) / tetrahydrofuran / 20 °C / Inert atmosphere 2.1: sodium hydroxide / ethanol; water / 1 h / Reflux 3.1: methanesulfonic acid / Heating 4.1: pyridine / dichloromethane / 20 °C 4.2: 20 °C / Cooling 5.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere 6.1: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C 7.1: platinum (II) chloride / toluene / Heating 8.1: boron tribromide 9.1: bis-[(trifluoroacetoxy)iodo]benzene View Scheme

1.1: sodium hydroxide / ethanol; water / 1 h / Reflux 2.1: methanesulfonic acid / Heating 3.1: pyridine / dichloromethane / 20 °C 3.2: 20 °C / Cooling 4.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere 5.1: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C 6.1: platinum (II) chloride / toluene / Heating 7.1: boron tribromide 8.1: bis-[(trifluoroacetoxy)iodo]benzene View Scheme

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere 2: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C 3: platinum (II) chloride / toluene / Heating 4: boron tribromide 5: bis-[(trifluoroacetoxy)iodo]benzene View Scheme