4,5,6,7-四氟-1H-吲哚-3-甲醛合成路线 （共 12 条）
反应条件
selenium(IV) oxide in diethylene glycol dimethyl ether T=160°C; 1.5 h;
参考文献
Fujita, Makoto; Ojima, Iwao
Tetrahedron Letters, 1983 , vol. 24, # 42 p. 4573 - 4576
反应条件
selenium(IV) oxide in diethylene glycol dimethyl ether T=160°C; 1.5 h;
参考文献
Ojima, Iwao; Kato, Koji; Nakahashi, Kazuaki; Fuchikami, Takamasa; Fujita, Makoto
Journal of Organic Chemistry, 1989 , vol. 54, # 19 p. 4511 - 4522
反应条件
trichlorophosphate in N,N-dimethyl-formamide T=35°C; 3 h;
参考文献
Filler, Robert; Woods, Sarah M.; White, William L.
Canadian Journal of Chemistry, 1989 , vol. 67, p. 1837 - 1841
反应条件
selenium(IV) oxide in diethylene glycol dimethyl ether T=160°C; 2 h; in sealed tube;
参考文献
Fujita, Makoto; Ojima, Iwao
Tetrahedron Letters, 1983 , vol. 24, # 42 p. 4573 - 4576
反应条件
1: 94 percent / pyridine / 1.5 h / Heating 2: 86 percent / selenium dioxide / bis-(2-methoxy-ethyl) ether / 1.5 h / 160 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 54, # 19 p. 4511 - 4522
反应条件
1: CHCl3 / 0.5 h / Ambient temperature 2: LDA / tetrahydrofuran / Ambient temperature; 1.) -78 deg C, 2.) RT, 10 h 3: 1.) RhCl3*3H2O, 2.) conc. HCl / 1.) ethanol, reflux, 14 h, 2.) reflux, 20 min 4: 94 percent / pyridine / 1.5 h / Heating 5: 86 percent / selenium dioxide / bis-(2-methoxy-ethyl) ether / 1.5 h / 160 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 54, # 19 p. 4511 - 4522
反应条件
1: 1.) RhCl3*3H2O, 2.) conc. HCl / 1.) ethanol, reflux, 14 h, 2.) reflux, 20 min 2: 94 percent / pyridine / 1.5 h / Heating 3: 86 percent / selenium dioxide / bis-(2-methoxy-ethyl) ether / 1.5 h / 160 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 54, # 19 p. 4511 - 4522
反应条件
selenium(IV) oxide in diethylene glycol dimethyl ether T=160°C; 2 h; in sealed tube; Yield given;
参考文献
Tetrahedron Letters, , vol. 24, # 42 p. 4573 - 4576
反应条件
1: LDA / tetrahydrofuran / Ambient temperature; 1.) -78 deg C, 2.) RT, 10 h 2: 1.) RhCl3*3H2O, 2.) conc. HCl / 1.) ethanol, reflux, 14 h, 2.) reflux, 20 min 3: 94 percent / pyridine / 1.5 h / Heating 4: 86 percent / selenium dioxide / bis-(2-methoxy-ethyl) ether / 1.5 h / 160 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 54, # 19 p. 4511 - 4522
反应条件
hydrogenchloride; amalgamated zinc in ethanol 0.5 h; Heating;
参考文献
Filler, Robert; Woods, Sarah M.; White, William L.
Canadian Journal of Chemistry, 1989 , vol. 67, p. 1837 - 1841
