1,3,5,7,9,11,14-七异丁基三环[7.3.3.15,11]七硅氧烷-内-3,7,14-三醇合成路线 （共 8 条）
反应条件
lithium hydroxide in methanol; water; acetone T=55°C; 18 h;
参考文献
CREAVIS GESELLSCHAFT FUeR TECHNOLOGIE UND INNOVATION MBH
Patent: WO2004/63207 A1, 2004 ;
Location in patent: Page/Page column 13-14 ;
反应条件
water; lithium hydroxide hydrate in acetone 20 h; Reflux;
参考文献
Zhou, Jinlan; Zhao, Yongchen; Yu, Kaichao; Zhou, Xingping; Xie, Xiaolin
New Journal of Chemistry, 2011 , vol. 35, # 12 p. 2781 - 2792
反应条件
triethylamine in methanol; toluene T=-10 - 50°C; Industry scale;
参考文献
ASAHI KASEI CHEMICALS CORPORATION
Patent: US2010/81837 A1, 2010 ;
Location in patent: Page/Page column 13 ;
反应条件
triethylamine in methanol; toluene T=25°C; 6 h; Industry scale;
参考文献
ASAHI KASEI CHEMICALS CORPORATION
Patent: US2010/81837 A1, 2010 ;
Location in patent: Page/Page column 14 ;
反应条件
in methanol; toluene
T=-10 - -5°C; Industry scale; Product distribution / selectivity;
参考文献
ASAHI KASEI CHEMICALS CORPORATION
Patent: US2010/81837 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
tetraethylammonium hydroxide in tetrahydrofuran; water
T=20°C;
参考文献
DEGUSSA AG
Patent: WO2006/27074 A1, 2006 ;
Location in patent: Page/Page column 14 ;
反应条件
triethylamine in pentane
T=0 - 20°C; Inert atmosphere;
参考文献
Zak, Patrycja; Pietraszuk, Cezary; Marciniec, Bogdan; Spolnik, Brzegorz; Danikiewicz, Witold
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 16 p. 2675 - 2682
反应条件
triethylamine in methanol; toluene
T=25°C; 6 h; Industry scale;
参考文献
ASAHI KASEI CHEMICALS CORPORATION
Patent: US2010/81837 A1, 2010 ;
Location in patent: Page/Page column 14 ;
