2-(4-甲氧基-2-甲基苯基)乙醇合成路线 （共 6 条）
反应条件
1: 98.5 percent / H2 / PtO2 / propan-2-ol / 2327.2 Torr 2: 1) conc. H2SO4, NaNO2, 2) CuBr, HBr / 1) H2O, 0-10 deg C, 2) H2O 3: 1) n-BuLi / 1) pentane, 5 psi, 6 h, 2) pentane, THF, 30 min View Scheme
参考文献
Young, David C.; Vouros, Paul; Holick, Michael F.; Higuchi, Tetsuo
Analytical Chemistry, 1992 , vol. 64, # 8 p. 837 - 842
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Ghatak,U.R.; Chatterjee,N.R.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 190 - 196
反应条件
1: 1) conc. H2SO4, NaNO2, 2) CuBr, HBr / 1) H2O, 0-10 deg C, 2) H2O 2: 1) n-BuLi / 1) pentane, 5 psi, 6 h, 2) pentane, THF, 30 min View Scheme
参考文献
Young, David C.; Vouros, Paul; Holick, Michael F.; Higuchi, Tetsuo
Analytical Chemistry, 1992 , vol. 64, # 8 p. 837 - 842
反应条件
n-butyllithium 1) pentane, 5 psi, 6 h, 2) pentane, THF, 30 min; Yield given. Multistep reaction;
参考文献
Young, David C.; Vouros, Paul; Holick, Michael F.; Higuchi, Tetsuo
Analytical Chemistry, 1992 , vol. 64, # 8 p. 837 - 842
反应条件
1: PBr3 / benzene 2: KOtBu / 2-methyl-propan-2-ol 3: aq. KOH / ethanol 4: (i) aq. EtOH, (ii) KOH, (iii) /BRN= 102415/, Et2O 5: (i) Et2O, (ii) polyphosphoric acid 6: Pd-C / 300 - 320 °C View Scheme
参考文献
Ghatak,U.R.; Chatterjee,N.R.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 190 - 196
反应条件
phosphorus tribromide in benzene
参考文献
Ghatak,U.R.; Chatterjee,N.R.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 190 - 196
