(2,5-二甲基苯基)溴化镁合成路线 （共 15 条）
反应条件
1: ortho-fluorobromobenzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h; Inert atmosphere;
2: 2,5-diMeC6H4MgBr in tetrahydrofuran; hexane
T=-78 - 20°C; Inert atmosphere;
参考文献
Laughlin, Brynna J.; Smith, Rhett C.
Macromolecules, 2010 , vol. 43, # 8 p. 3744 - 3749
反应条件
2: aqueous HCl; acetic acid
3: chloranil; xylene
View Scheme
参考文献
Weisburger; Weisburger
Journal of Organic Chemistry, 1958 , vol. 23, p. 1193,1197
反应条件
2: aqueous HCl; acetic acid
3: chloranil; xylene
4: KMnO4
5: polyphosphoric acid
6: N2H4+H2O; NaOH
View Scheme
参考文献
Weisburger; Weisburger
Journal of Organic Chemistry, 1958 , vol. 23, p. 1193,1197
反应条件
1: diethyl ether / -60 °C
2: sodium / man verseift den entstandenen Ester
View Scheme
参考文献
Gattermann
Justus Liebigs Annalen der Chemie, 1912 , vol. 393, p. 224
反应条件
diethyl ether; sulfur
参考文献
Taboury
Annales de Chimie (Cachan, France), 1908 , vol. <8>15, p. 18,36,41
Bulletin de la Societe Chimique de France, 1906 , vol. <3>35, p. 673
