6-氨基-6-脱氧-alpha-D-吡喃葡萄糖基6-氨基-6-脱氧-alpha-D-吡喃葡萄糖苷合成路线 （共 11 条）
反应条件
triphenylphosphine in N,N-dimethyl-formamide 2 h;
参考文献
Baddeley, Thomas C.; Davidson, Iain G.; Glidewell, Christopher; Low, John N.; Skakle, Janet M. S.; Wardell, James L.
Acta Crystallographica Section B: Structural Science, 2004 , vol. 60, # 4 p. 461 - 471
反应条件
1: 67 percent / sodium methoxide / methanol / 4.5 h 2: 60 percent / triphenylphosphine / dimethylformamide / 2 h View Scheme
参考文献
Menger; Mbadugha
Journal of the American Chemical Society, 2001 , vol. 123, # 5 p. 875 - 885
反应条件
1: 64 percent / DMPU; NaN3 / 6 h / 90 °C 2: 94 percent / NaOMe; MeOH / 20 °C 3: PPh3; MeOH / dioxane / 1 h View Scheme
参考文献
Menger; Mbadugha
Journal of the American Chemical Society, 2001 , vol. 123, # 5 p. 875 - 885
反应条件
Yield given. Multistep reaction;
参考文献
Rose, Jerry D.; Maddry, Joseph A.; Comber, Robert N.; Suling, William J.; Wilson, Larry N.; Reynolds, Robert C.
Carbohydrate Research, 2002 , vol. 337, # 2 p. 105 - 120
反应条件
1: 90 percent / NaN3 / dimethylformamide / 14 h / 65 °C 2: 73 percent / NaOMe / methanol / 48 h / 20 °C 3: 25 percent / H2 / Pd/C / methanol / 27 h View Scheme
参考文献
Rose, Jerry D.; Maddry, Joseph A.; Comber, Robert N.; Suling, William J.; Wilson, Larry N.; Reynolds, Robert C.
Carbohydrate Research, 2002 , vol. 337, # 2 p. 105 - 120
反应条件
1: 80 percent / pyridine / 64 h / 20 °C 2: 80 percent / NBS; K2CO3 / CCl4 / 2 h / Heating 3: 90 percent / NaN3 / dimethylformamide / 14 h / 65 °C 4: 73 percent / NaOMe / methanol / 48 h / 20 °C 5: 25 percent / H2 / Pd/C / methanol / 27 h View Scheme
参考文献
Rose, Jerry D.; Maddry, Joseph A.; Comber, Robert N.; Suling, William J.; Wilson, Larry N.; Reynolds, Robert C.
Carbohydrate Research, 2002 , vol. 337, # 2 p. 105 - 120
反应条件
1: 80 percent / NBS; K2CO3 / CCl4 / 2 h / Heating 2: 90 percent / NaN3 / dimethylformamide / 14 h / 65 °C 3: 73 percent / NaOMe / methanol / 48 h / 20 °C 4: 25 percent / H2 / Pd/C / methanol / 27 h View Scheme
参考文献
Rose, Jerry D.; Maddry, Joseph A.; Comber, Robert N.; Suling, William J.; Wilson, Larry N.; Reynolds, Robert C.
Carbohydrate Research, 2002 , vol. 337, # 2 p. 105 - 120
反应条件
1: 73 percent / NaOMe / methanol / 48 h / 20 °C 2: 25 percent / H2 / Pd/C / methanol / 27 h View Scheme
参考文献
Rose, Jerry D.; Maddry, Joseph A.; Comber, Robert N.; Suling, William J.; Wilson, Larry N.; Reynolds, Robert C.
Carbohydrate Research, 2002 , vol. 337, # 2 p. 105 - 120
反应条件
1: 94 percent / sodium azide / dimethylsulfoxide / 1 h / 76.85 °C 2: 67 percent / sodium methoxide / methanol / 4.5 h 3: 60 percent / triphenylphosphine / dimethylformamide / 2 h View Scheme
参考文献
Baddeley, Thomas C.; Davidson, Iain G.; Glidewell, Christopher; Low, John N.; Skakle, Janet M. S.; Wardell, James L.
Acta Crystallographica Section B: Structural Science, 2004 , vol. 60, # 4 p. 461 - 471
反应条件
1: 92 percent / pyridine / acetonitrile / 3 h 2: 94 percent / sodium azide / dimethylsulfoxide / 1 h / 76.85 °C 3: 67 percent / sodium methoxide / methanol / 4.5 h 4: 60 percent / triphenylphosphine / dimethylformamide / 2 h View Scheme
参考文献
Baddeley, Thomas C.; Davidson, Iain G.; Glidewell, Christopher; Low, John N.; Skakle, Janet M. S.; Wardell, James L.
Acta Crystallographica Section B: Structural Science, 2004 , vol. 60, # 4 p. 461 - 471
