potassium carbonate

potassium carbonate in N,N-dimethyl-formamide T=20°C; 5 h;

sodium hydrogencarbonate in water T=20 - 23°C;

1: With lithium aluminium tetrahydride in tetrahydrofuran T=-10°C; 1 h; 2: With sodium hydroxide in tetrahydrofuran; water

1: 3-ethyl 1-(phenylmethyl) 1,3-piperidinedicarboxylate With lithium hexamethyldisilazane in tetrahydrofuran T=-78°C; 0.333333 h; 2: methyl iodide in tetrahydrofuran T=-78 - 20°C;

1: With lithium hexamethyldisilazane in tetrahydrofuran T=-78°C; 0.583333 h; 2: With methyl iodide in tetrahydrofuran T=-78 - 20°C;

1.1: N,N'-dimethyl-N,N'-propyleneurea; lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 - -60 °C 1.2: 2.5 h / -60 - -20 °C 2.1: hydrogen; 5 palladium on charcoal / methanol; ethyl acetate / 1.5 h View Scheme

1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / -10 °C 2: sodium hydrogencarbonate; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical / dichloromethane; water / 18 h / 20 °C View Scheme

1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / -10 °C 2: sodium hydrogencarbonate; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical / dichloromethane; water / 18 h / 20 °C 3: potassium carbonate; toluene-4-sulfonic acid; toluene-4-sulfonamide / toluene; ethylene glycol dimethyl ether; methanol / 20 h / 80 °C 4: hydrogenchloride / 1,4-dioxane; water / 16 h / 80 °C View Scheme

diphenyl phosphoryl azide; triethylamine T=20 - 100°C; 21.5 h;